2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione

Base Information

Chemical Name:2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione
CAS No.:82939-76-2
Molecular Formula:C₁₅H₂₄O₅
Molecular Weight:284.353
Hs Code.:

Synonyms:2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione

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Chemical Property of 2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione

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Technology Process of 2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione

There total 5 articles about 2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.3%

: 82939-72-8
6-But-3-enyl-1,5-dimethoxy-6-(2-methoxy-ethoxymethoxymethyl)-cyclohexa-1,4-diene

: 82939-76-2
2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione

Guidance literature:: With toluene-4-sulfonic acid; In acetone; at 0 ℃; for 1h;
DOI:10.1039/c39820000502

Reference yield:

: 58310-18-2
1,4-dihydro-2,6-dimethoxybenzoic acid

: 82939-76-2
2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / K₂CO₃ / acetone / 6 h / Heating

2: 1.) (i-Pr)2NLi / 1.) THF, hexane, 0 deg C, 5 min, 2.) 0 deg C, 25 h

3: 97.3 percent / LiAlH₄ / tetrahydrofuran; diethyl ether / 1 h / Ambient temperature

4: (i-Pr)2NEt / CH₂Cl₂ / 7 h / Ambient temperature

5: 90.3 percent / p-TsOH*H₂O / acetone / 1 h / 0 °C

With lithium aluminium tetrahydride; potassium carbonate; toluene-4-sulfonic acid; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; dichloromethane; acetone;

Reference yield:

: 82939-66-0
methyl 2,6-dimethoxy-2,5-cyclohexadiene-1-carboxylate

: 82939-76-2
2-(but-1-en-4-yl)-2-<<(2-methoxyethoxy)methoxy>methyl>cyclohexane-1,3-dione

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) (i-Pr)2NLi / 1.) THF, hexane, 0 deg C, 5 min, 2.) 0 deg C, 25 h

2: 97.3 percent / LiAlH₄ / tetrahydrofuran; diethyl ether / 1 h / Ambient temperature

3: (i-Pr)2NEt / CH₂Cl₂ / 7 h / Ambient temperature

4: 90.3 percent / p-TsOH*H₂O / acetone / 1 h / 0 °C

With lithium aluminium tetrahydride; toluene-4-sulfonic acid; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; dichloromethane; acetone;