ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate

Base Information

Chemical Name:ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate
CAS No.:1361519-45-0
Molecular Formula:C₁₃H₁₃F₃N₂O₁₀S
Molecular Weight:446.315
Hs Code.:

Synonyms:ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate

Chemical Property:

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Technology Process of ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate

There total 13 articles about ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 1361519-42-7
ethyl 3-(3-hydroxy-4-methoxy-2,6-dinitrophenyl)propanoate

: 1361519-45-0
ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; Inert atmosphere;
DOI:10.1002/chem.201102732

Reference yield:

: 3-(3-hydroxy-4-methoxy-2,6-dinitrophenyl)propanoic acid

: 1361519-45-0
ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate

Guidance literature:: Multi-step reaction with 2 steps

1: sulfuric acid / Reflux

2: triethylamine / dichloromethane / 0 °C / Inert atmosphere

With sulfuric acid; triethylamine; In dichloromethane;
DOI:10.1002/chem.201102732

Reference yield:

: 1361519-61-0
ethyl 2-(3-hydroxy-4-methoxy-2,6-dinitrophenyl)acetate

: 1361519-45-0
ethyl 3-(4-methoxy-2,6-dinitro-3-(trifluoromethylsulfonyloxy)phenyl)propanoate

Guidance literature:: Multi-step reaction with 7 steps

1: potassium carbonate / acetone / 22 h / Reflux

2: water; sodium hydroxide / 1,4-dioxane; ethanol / 0.58 h / 20 °C

3: thionyl chloride / chloroform / 1 h / Reflux

4: tetrahydrofuran; diethyl ether / 1.17 h / 0 - 20 °C / Inert atmosphere

5: silver benzoate; triethylamine / tetrahydrofuran / 3.5 h / 20 °C / Inert atmosphere; Darkness

6: palladium 10% on activated carbon; hydrogen / 1,4-dioxane / 0.58 h / 517.16 Torr

7: triethylamine / dichloromethane / 0 °C / Inert atmosphere

With thionyl chloride; palladium 10% on activated carbon; water; hydrogen; silver benzoate; potassium carbonate; triethylamine; sodium hydroxide; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; dichloromethane; chloroform; acetone;
DOI:10.1002/chem.201102732