[(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)]

Base Information

• Chemical Name: [(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)]
• CAS No.: 801221-16-9
• Molecular Formula: C₂₈H₅₆BFeP₃
• Molecular Weight: 552.332
• Mol file: 801221-16-9.mol

Synonyms:[(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)]

Chemical Property of [(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)]

Chemical Property:

Purity/Quality:

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Technology Process of [(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)]

There total 1 articles about [(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

{[PhBP3iPr]}FeCl (579444-62-5) + methyllithium (917-54-4) → [(phenyl)B(CH2P(iPr)2)3(methyl)iron(II)] (801221-16-9)

Guidance literature:

In tetrahydrofuran; diethyl ether; (N2); Schlenk technique; soln. of MeLi in Et2O was added to frozen soln.of Fe compd. in THF; soln. was allowed to thaw to room temp. and stirre d for 1 h; THF removed (vac.); extd. (C6H6); filtered; extract dried (vac.); dissolved in toluene; filtered; stored at -25°C; elem. anal.;

DOI:10.1021/ic0488583

Reference yield: 99.0%

[(phenyl)B(CH2P(iPr)2)3(methyl)iron(II)] (801221-16-9) + (2,4,6-trimethylphenyl)silane (120578-34-9) → [iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methyl)(2,4,6-(methyl)3C6H2)] (881087-53-2)

Guidance literature:

In benzene; reactn. of Fe compex with (CH3)3C6H2SiH3 (1:1 molar ratio) at room temp.for 30 min; detd. by (1)H NMR;

DOI:10.1002/anie.200502527

Reference yield: 99.0%

[(phenyl)B(CH2P(iPr)2)3(methyl)iron(II)] (801221-16-9) + phenylsilane (694-53-1) → [iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))] (881087-52-1)

Guidance literature:

In benzene; reactn. of Fe compex with C6H5SiH3 at room temp. for 30 min; detd. by (1)H NMR;

DOI:10.1002/anie.200502527

upstream raw materials:

{[PhBP₃^iPr]}FeCl

methyllithium

Downstream raw materials:

[(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(P(CH₃)3)]

(PhB(CH₂P^iPr₂)₃)Fe(H)₃(PMe₃)

[iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))]

[(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(H)3(P(C₂H₅)3)]

Refernces