881087-52-1

Basic information

• Product Name: [iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))]
• Synonyms: [iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))]
• CAS NO: 881087-52-1
• Molecular Weight: 660.547
• Mol File: 881087-52-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))](CAS DataBase Reference)
• NIST Chemistry Reference: [iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))](881087-52-1)
• EPA Substance Registry System: [iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))](881087-52-1)

Safety Data

• Hazardous Substances Data: 881087-52-1(Hazardous Substances Data)

Upstream product

• 801221-16-9 [(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)] 
• 694-53-1 phenylsilane 
• 766-08-5 methylphenylsilane 
• 1333-74-0 hydrogen 

Relevant articles and documents

An η3-H2SiR2 adduct of [{PhB-(CH 2PiPr2)3}FeIIH]

Reaction of the high-spin iron(II) alkyl complex [{PhB(CH 2PiPr2)3}FeMe] with phenylsilane or mesitylsilane affords unusual diamagnetic silane adducts of the iron(II) hydride [{PhB(CH2PiPr2)3}FeH]. An η3 bonding mode in these silane adducts has been established by NMR spectroscopy, X-ray crystallography, and DFT methods. Rapid interconversion ofs the hydride positions in solution via a silylene intermediate is proposed. (Chemical Equation Presented)