3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose

Base Information

Chemical Name:3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose
CAS No.:99784-34-6
Molecular Formula:C₁₆H₂₁NO₆
Molecular Weight:323.346
Hs Code.:

Synonyms:3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose

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Chemical Property of 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose

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Technology Process of 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose

There total 7 articles about 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 86495-59-2
(E)-3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-α-D-xylo-hex-5-eno-1,4-furanose

: 99784-34-6
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose

Guidance literature:: With sodium tetrahydroborate; In methanol; water; for 5h; Ambient temperature;
DOI:10.1021/jo00352a028

Reference yield:

: 41545-33-9,41545-34-0,69177-81-7,69177-82-8,78283-48-4,78283-49-5,83603-28-5
3-O-benzyl-6-deoxy-1,2-O-isopropylidene-6-C-nitro-α-L-idofuranose

: 99784-34-6
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / Et₃N, MeSO₂Cl / diethyl ether / 1.) 0 deg C, 30 min, 2.) RT, 5 h

2: 95 percent / NaBH₄ / H₂O; methanol / 5 h / Ambient temperature

With sodium tetrahydroborate; methanesulfonyl chloride; triethylamine; In methanol; diethyl ether; water;
DOI:10.1021/jo00352a028

Reference yield:

: 350255-13-9
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 99784-34-6
3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose

Guidance literature:: Multi-step reaction with 5 steps

1: sodium hydride / N,N-dimethyl-formamide

2: sodium periodate / methanol; water

3: sodium hydroxide / ethanol

4: methanesulfonyl chloride; triethylamine / dichloromethane

5: sodium tetrahydroborate / ethanol

With sodium tetrahydroborate; sodium periodate; sodium hydride; methanesulfonyl chloride; triethylamine; sodium hydroxide; In methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; 3: Henry reaction;
DOI:10.1002/cbic.201100229