86495-59-2Relevant academic research and scientific papers
CHIRALE SYNTHESE VON (+)-LYCORICIDIN
Paulsen, Hans,Stubbe, Matthias
, p. 3171 - 3174 (1982)
The synthesis of (+)-lycoricidine from D-glucose is described.Addition of the carbanion 11 to the nitroolefine 10 yields the adduct 12+13, from which crystalline lactone 16 with muco-configuration in the cyclitol-ring can be isolated after hydrolysis and
Solvent and catalyst free route to 3-indolyl glycoconjugates: Synthesis of sugar tethered isoxazolines and isoxazoles from 3-indolyl nitroalkanes
Karthikeyan,Kumar, R. Senthil,Dheenkumar,Perumal, Paramasivan T.
, p. 27988 - 27997 (2014/07/21)
An expedient, solvent and catalyst free strategy for the synthesis of sugar based bis(indolyl)methanes and indolyl nitroalkanes has been developed. The protocol works well within a wide range of substrates, and tolerates various N/O protecting groups. The
Glycosynthase-Mediated Assembly of Xylanase Substrates and Inhibitors
Goddard-Borger, Ethan D.,Fiege, Brigitte,Kwan, Emily M.,Withers, Stephen G.
, p. 1703 - 1711 (2012/06/29)
An exo-β-xylosidase mutant with glycosynthase activity was created to aid in the synthesis of xylanase substrates and inhibitors. Simple monosaccharides were easily elaborated into di-, tri- and tetrasaccharides by using this enzyme. Some products proved
Synthesis of densely functionalised C-glycosides by a tandem oxy Michael addition-Wittig olefination pathway
Senthil Kumar,Karthikeyan,Phani Kumar,Muralidharan,Perumal
experimental part, p. 457 - 461 (2010/04/24)
Wittig olefination of 5,6-dideoxy-5,6-anhydro-6-nitro-d-glucofuranose (5) triggered a concomitant cyclisation via oxy Michael addition of the C2-hydroxyl group resulting in the formation of C-vinyl glycosides with Z-olefinic geometry.
