(R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester

Base Information

Chemical Name:(R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester
CAS No.:183384-69-2
Molecular Formula:C₂₀H₂₈O₄
Molecular Weight:332.44
Hs Code.:

Synonyms:(R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester

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Chemical Property of (R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester

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Technology Process of (R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester

There total 8 articles about (R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 24850-33-7
allyltributylstanane

: 183384-63-6
(R)-(-)-2,4-dimethoxy-6-trifluoromethylsulfonyloxybenzoic acid (1-methyl-hept-7-enyl)ester

: 183384-69-2
(R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester

Guidance literature:: With 1-methyl-pyrrolidin-2-one; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; trifuran-2-yl-phosphane; lithium chloride; at 40 ℃;
DOI:10.1016/0040-4039(96)01590-0

Reference yield:

: 3187-19-7
2,4-dimethoxysalicylic acid

: 183384-69-2
(R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / EtOOC-N=N-COOEt; PPh₃ / diethyl ether / 25 °C

2: 91 percent / pyridine / 0 - 25 °C

3: 93 percent / LiCl / Pd₂(dba)3/tris(2-furyl)phosphine / 1-methyl-pyrrolidin-2-one / 120 h / 40 °C

With pyridine; triphenylphosphine; lithium chloride; diethylazodicarboxylate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; trifuran-2-yl-phosphane; In 1-methyl-pyrrolidin-2-one; diethyl ether; 1: Esterification / 2: Esterification / 3: Stille cross coupling reaction;
DOI:10.1016/S0040-4020(99)00302-6

Reference yield:

: 129234-94-2
(S)-2-hydroxy-7-octene

: 183384-69-2
(R)-(-)-2-propen-1-yl-4,6-dimethoxybenzoic acid (1-methyl-hept-6-enyl)ester

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / EtOOC-N=N-COOEt; PPh₃ / diethyl ether / 25 °C

2: 91 percent / pyridine / 0 - 25 °C

3: 93 percent / LiCl / Pd₂(dba)3/tris(2-furyl)phosphine / 1-methyl-pyrrolidin-2-one / 120 h / 40 °C

With pyridine; triphenylphosphine; lithium chloride; diethylazodicarboxylate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; trifuran-2-yl-phosphane; In 1-methyl-pyrrolidin-2-one; diethyl ether; 1: Esterification / 2: Esterification / 3: Stille cross coupling reaction;
DOI:10.1016/S0040-4020(99)00302-6