1-mercapto-7-phenyl-meta-carborane anion

Base Information

Chemical Name:1-mercapto-7-phenyl-meta-carborane anion
CAS No.:778595-97-4
Molecular Formula:C₈H₁₆B₁₀S
Molecular Weight:252.391
Hs Code.:

Synonyms:1-mercapto-7-phenyl-meta-carborane anion

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Chemical Property of 1-mercapto-7-phenyl-meta-carborane anion

Chemical Property:

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Technology Process of 1-mercapto-7-phenyl-meta-carborane anion

There total 1 articles about 1-mercapto-7-phenyl-meta-carborane anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 16351-47-6
1-phenyl-1,7-dicarba-closo-dodecaborane⁽¹²⁾

: 7704-34-9
sulfur

: 778595-97-4
1-mercapto-7-phenyl-meta-carborane anion

Guidance literature:: With sodium; iron(III) nitrate nonahydrate; HCl; In hexane; ammonia; NH3 (liquid); under N2 atm. Fe(NO3)3*9H2O and Na were added to liq. ammonia at -40°C and stirred for 30 min, soln. 1-phenyl-meta-carborane in hexane was added, after 1 h powdered sulfur was added, react. mixt. was evapd. for 8 h at room temp.; EtOH and water were added, react. mixt. was concd., soln. was filtered through charcoal, acidified with HCl, extd. with hexane, washed with aq. KHCO3., dried over MgSO4, solvent was removed, residue was distilled at 100°C/0.05 mm Hg; elem. anal.;
DOI:10.1039/b406422d

Reference yield:

: 778595-97-4
1-mercapto-7-phenyl-meta-carborane anion

: 20734-58-1
N,N,N',N'-tetramethyl-1,8-diaminonaphthalene

: 1-mercapto-7-phenyl-1,7-carborane - proton sponge adduct 1:1

Guidance literature:: In hexane; under N2 atm. soln. proton sponge in hexane was added dropwise to soln. 1-mercapto-7-phenyl-meta-carborane in hexane; ppt. was filtered off, washed with hexane and recrystd. from hexane-toluene (1:1); elem. anal.;
DOI:10.1039/b406422d