(S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene

Base Information

Chemical Name:(S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene
CAS No.:221493-43-2
Molecular Formula:C₂₇H₃₉N₃O₄S
Molecular Weight:501.69
Hs Code.:

Synonyms:(S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene

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Chemical Property of (S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene

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Technology Process of (S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene

There total 7 articles about (S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: N-[1-[(S)-1-(2-Benzyloxy-ethyl)-5-methyl-hex-4-enylamino]-1-methylsulfanyl-meth-(Z)-ylidene]-4-methoxy-2,3,6-trimethyl-benzenesulfonamide

: 221493-43-2
(S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene

Guidance literature:: With ammonia; silver nitrate; In acetonitrile; at 0 - 20 ℃; for 18h; Yield given;
DOI:10.1021/jo981972g

Reference yield:

: 100-39-0
benzyl bromide

: 221493-43-2
(S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / NaH / dimethylformamide / 1 h / -40 - -10 °C

2: HN₃, DEAD, PPh₃ / toluene / 0 °C

3: 4.53 g / LiAlH₄ / diethyl ether / 0 - 20 °C

4: benzene / 2 h / Heating

5: NH₃, AgNO₃ / acetonitrile / 18 h / 0 - 20 °C

With lithium aluminium tetrahydride; tris-(2-chloro-ethyl)-amine; ammonia; sodium hydride; silver nitrate; triphenylphosphine; diethylazodicarboxylate; In diethyl ether; N,N-dimethyl-formamide; toluene; acetonitrile; benzene;
DOI:10.1021/jo981972g

Reference yield:

: 93041-02-2
(3R)-1,2-dihydroxy-7-methyloct-6-ene

: 221493-43-2
(S)-N-<(aminomethylene)-4-methoxy-2,3,6-trimethylbenzenesulfonamide>-3-amino-1-benzyloxy-7-methyl-6-octene

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / NaH / dimethylformamide / 1 h / -40 - -10 °C

2: HN₃, DEAD, PPh₃ / toluene / 0 °C

3: 4.53 g / LiAlH₄ / diethyl ether / 0 - 20 °C

4: benzene / 2 h / Heating

5: NH₃, AgNO₃ / acetonitrile / 18 h / 0 - 20 °C

With lithium aluminium tetrahydride; tris-(2-chloro-ethyl)-amine; ammonia; sodium hydride; silver nitrate; triphenylphosphine; diethylazodicarboxylate; In diethyl ether; N,N-dimethyl-formamide; toluene; acetonitrile; benzene;
DOI:10.1021/jo981972g