cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)₂]

Base Information

• Chemical Name: cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)₂]
• CAS No.: 1147863-02-2
• Molecular Formula: C₃₃H₂₈N₄P₂PdS₂
• Molecular Weight: 713.112
• Mol file: 1147863-02-2.mol

Synonyms:cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)₂]

Chemical Property of cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)₂]

There total 3 articles about cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-thioxopyrimidine (1450-85-7) + bis-diphenylphosphinomethane (2071-20-7) + palladium dichloride → cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)2] (1147863-02-2)

Guidance literature:

2-thioxopyrimidine; With potassium hydroxide; In methanol;

bis-diphenylphosphinomethane; palladium dichloride; In methanol; at 60 ℃; for 48h;

DOI:10.1016/j.poly.2015.04.007

Reference yield: 70.0%

2-thioxopyrimidine (1450-85-7) + (bis(diphenylphosphino)methane)palladium(II) dichloride (38425-01-3) → cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)2] (1147863-02-2)

Guidance literature:

With NaOH; In ethanol; water; byproducts: NaCl; aq. NaOH added to solid pyrimidinethione, suspn. of Pd compd. in ethanoladded, soln. refluxed for 10 h; filtration, filtrate stored at room temp. for 5 d, crystals sepd.; elem.anal.;

DOI:10.1002/zaac.200700482

Reference yield:

bis-diphenylphosphinomethane (2071-20-7) → cis-[Pd(bis(diphenylphosphino)methane)(pyrimidine2-thiolate)2] (1147863-02-2)

Guidance literature:

Multi-step reaction with 2 steps

1: acetonitrile

2: NaOH / water; ethanol

With NaOH; In ethanol; water; acetonitrile;

DOI:10.1002/zaac.200700482

upstream raw materials:

2-thioxopyrimidine

(bis(diphenylphosphino)methane)palladium(II) dichloride

bis-diphenylphosphinomethane