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12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene

Base Information Edit
  • Chemical Name:12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene
  • CAS No.:77061-16-6
  • Molecular Formula:C34H23BrO4
  • Molecular Weight:575.458
  • Hs Code.:
  • Mol file:77061-16-6.mol
12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzo<j>fluoranthene

Synonyms:12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene

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Chemical Property of 12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene Edit
Chemical Property:
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Technology Process of 12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene

There total 12 articles about 12-bromo-9α,10β-bis(benzoyloxy)-9,10,11,12-tetrahydrobenzofluoranthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With N-Bromosuccinimide; azobisisobutyronitrile; In tetrachloromethane; for 2h; Heating;
DOI:10.1021/jo00325a028
Guidance literature:
Multi-step reaction with 12 steps
1: 80 percent / DDQ / xylene / 5 h / Heating
2: 80 percent / N-bromosuccinimide, benzoyl peroxide / CCl4 / 3 h / Heating
3: 78 percent / diethyl ether / 30 h / Heating
4: 1.) diborane, 2.) 30percent H2O2 / 1.) THF, from 0 deg C to room temp., 8 h, 2.) reflux, 1 h
5: pyridinium chlorochromate / CH2Cl2 / 1 h / 20 °C
6: 85 percent / AgNO3, 1.5 KOH / ethanol; H2O / 2 h
7: SOCl2 / benzene / 3 h / Heating
8: 1.) AlCl3 / CS2 / 1.) 0 deg C, 2.) reflux, 10 min
9: LiAlH4 / tetrahydrofuran / 0.33 h / 20 °C
10: 60 percent / conc. H2SO4 / acetic acid / 3 h / 60 °C
11: 62 percent / 1.) I2 / benzene / 1.) reflux, 2.) reflux, 2.5 h
12: 30 percent / N-bromsuccinimide, α,α'-azobis(isobutyronitrile) / CCl4 / 2 h / Heating
With potassium hydroxide; N-Bromosuccinimide; lithium aluminium tetrahydride; aluminium trichloride; thionyl chloride; Perbenzoic acid; sulfuric acid; azobisisobutyronitrile; dihydrogen peroxide; iodine; silver nitrate; pyridinium chlorochromate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; diborane; In tetrahydrofuran; carbon disulfide; tetrachloromethane; diethyl ether; ethanol; dichloromethane; water; acetic acid; xylene; benzene;
DOI:10.1021/jo00325a028
Guidance literature:
Multi-step reaction with 11 steps
1: 80 percent / N-bromosuccinimide, benzoyl peroxide / CCl4 / 3 h / Heating
2: 78 percent / diethyl ether / 30 h / Heating
3: 1.) diborane, 2.) 30percent H2O2 / 1.) THF, from 0 deg C to room temp., 8 h, 2.) reflux, 1 h
4: pyridinium chlorochromate / CH2Cl2 / 1 h / 20 °C
5: 85 percent / AgNO3, 1.5 KOH / ethanol; H2O / 2 h
6: SOCl2 / benzene / 3 h / Heating
7: 1.) AlCl3 / CS2 / 1.) 0 deg C, 2.) reflux, 10 min
8: LiAlH4 / tetrahydrofuran / 0.33 h / 20 °C
9: 60 percent / conc. H2SO4 / acetic acid / 3 h / 60 °C
10: 62 percent / 1.) I2 / benzene / 1.) reflux, 2.) reflux, 2.5 h
11: 30 percent / N-bromsuccinimide, α,α'-azobis(isobutyronitrile) / CCl4 / 2 h / Heating
With potassium hydroxide; N-Bromosuccinimide; lithium aluminium tetrahydride; aluminium trichloride; thionyl chloride; Perbenzoic acid; sulfuric acid; azobisisobutyronitrile; dihydrogen peroxide; iodine; silver nitrate; pyridinium chlorochromate; diborane; In tetrahydrofuran; carbon disulfide; tetrachloromethane; diethyl ether; ethanol; dichloromethane; water; acetic acid; benzene;
DOI:10.1021/jo00325a028
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