(CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)

Base Information

Chemical Name:(CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)
CAS No.:105371-68-4
Molecular Formula:C₃₆H₃₃O₄P₂RhW
Molecular Weight:878.359
Hs Code.:

(CO)4W(P(C<sub>6</sub>H<sub>5</sub>)2)2Rh(C<sub>8</sub>H<sub>13</sub>)

Synonyms:(CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)

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Chemical Property of (CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)

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Technology Process of (CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)

There total 2 articles about (CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 70505-43-0
cis-W(CO)4(PPh₂H)2

: 105371-68-4
(CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)

Guidance literature:: With n-butyllithium; p-toluenesulfonic acid; In diethyl ether; Et2O soln. of Li2(W(CO)4(PPh2)2) generated in situ from W(CO)4(PPh2H)2 and 2.0 equiv of n-BuLi was added to a suspn. of (Rh(μ-Cl)(COD))2 in Et2O, soln. of Li((CO)4W(PPh2)2Rh(COD)) was stirred for 2 h, p-TsOH in THF added; filtered through Celite, Et2O removed in vac., further purifn. included extn. with isopentane in a Soxhlet extractor and recrystn. from Et2O;

Reference yield:

: 105335-65-7
(CO)4W(P(C₆H₅)2)2Rh(H)(C₈H₁₂)

: 105371-68-4
(CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)

Guidance literature:: With air; In tetrahydrofuran; exposing to air or prolonged standing in soln. under N2;

Reference yield: 47.3%

: 105371-68-4
(CO)4W(P(C₆H₅)2)2Rh(C₈H₁₃)

: 105335-70-4
C₅₈H₄₀O₁₀P₄Rh₂W₂, triclinic

Guidance literature:: With carbon monoxide; In dichloromethane; soln. of the dinuclear complex in CH2Cl2 stirred at room temp. under atmosphere of CO (pressure 90 psi) for 4 h; gas was vented, solvent evapd., residue chromd. on basic alumina (eluant CH2Cl2/hexane (20/80)); elem. anal.; one more unidentified compound was formed;