3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene

Base Information

Chemical Name:3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene
CAS No.:443096-50-2
Molecular Formula:C₄₀H₇₀GeSi₆
Molecular Weight:792.099
Hs Code.:

Synonyms:3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene

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Chemical Property of 3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene

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Technology Process of 3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene

There total 8 articles about 3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 443096-40-0
1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabenzene

: 536-74-3
phenylacetylene

: 443096-50-2
3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene

Guidance literature:: In benzene-d6; under Ar; C6H5CCH added to the germabenzene dissolved in C6D6, heated at80°C for 108 h; solvent removed, GPLC (CHCl3) and PTLC (hexane/CHCl3 (3/1)); elem. anal.;
DOI:10.1021/ja0262941

Reference yield:

: 5-iodopenta-1,4-dienyl(dimethoxy)(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)germane

: 443096-50-2
3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene

Guidance literature:: Multi-step reaction with 4 steps

1: tert-butyllithium; HCl; SiO₂ / diethyl ether; pentane

2: diethyl ether

3: lithium diisopropylamide / tetrahydrofuran; n-heptane; ethylbenzene

4: benzene-d6

With tert-butyllithium; HCl; SiO₂; lithium diisopropylamide; In tetrahydrofuran; diethyl ether; n-heptane; ethylbenzene; benzene-d6; pentane;
DOI:10.1021/ja0262941

Reference yield:

: 443096-41-1
trimethoxy(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)germane

: 443096-50-2
3-phenyl-1-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-1-germabicyclo[2.2.2]octa-2,5,7-triene

Guidance literature:: Multi-step reaction with 6 steps

1: NH₄Cl / diethyl ether; hexane

2: Na₂S₂O₃ / dichloromethane

3: tert-butyllithium; HCl; SiO₂ / diethyl ether; pentane

4: diethyl ether

5: lithium diisopropylamide / tetrahydrofuran; n-heptane; ethylbenzene

6: benzene-d6

With NH₄Cl; Na₂S₂O₃; tert-butyllithium; HCl; SiO₂; lithium diisopropylamide; In tetrahydrofuran; diethyl ether; hexane; n-heptane; dichloromethane; ethylbenzene; benzene-d6; pentane;
DOI:10.1021/ja0262941