[bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate

Base Information

• Chemical Name: [bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate
• CAS No.: 112220-39-0
• Molecular Formula: 2CF₃O₃S*C₄₅H₅₃O₃P₃RuS₂
• Molecular Weight: 1198.18
• Mol file: 112220-39-0.mol

Synonyms:[bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate

Chemical Property of [bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate

There total 2 articles about [bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

[tris(μ-chloro)bis((triphos)ruthenium(II))] chloride (103500-17-0) + silver trifluoromethanesulfonate (2923-28-6) + dimethyl sulfoxide (67-68-5,8070-53-9) → [bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate (112220-39-0) + [tris(dimethylsulfoxide-O)(triphos)ruthenium(II)] triflate (112220-35-6)

Guidance literature:

In methanol; byproducts: AgCl; refluxed in the dark for 2 h; filtered, concd. (vac.), diethyl ether added dropwise, stored at room temp. for 24 h, ppt. filtered, washed (diethyl ether), dried (vac.); elem.anal.;

DOI:10.1002/ejic.200400717

Reference yield:

fac-[tris(dimethylsulfoxide-S)tris(dimethylsulfoxide-O)ruthenium(II)] triflate + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → [bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate (112220-39-0) + [tris(dimethylsulfoxide-O)(triphos)ruthenium(II)] triflate (112220-35-6)

Guidance literature:

In methanol; refluxed in methanol, or in acetone, or in toluene, or in nitromethane;

DOI:10.1002/ejic.200400717

Reference yield: 90.0%

[bis(dimethylsulfoxide-O)(triphos)aquaruthenium(II)] triflate (112220-39-0) → Ru(CF3SO3)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)*CF3SO3(1-)={Ru(CF3SO3)(CO)2(CH3C(CH2P(C6H5)2)3)}(CF3SO3) (112220-44-7) + dimethyl sulfoxide (67-68-5,8070-53-9)

Guidance literature:

With CO; In dichloromethane; byproducts: H2O; stirring of soln. under CO atmosphere (15 min); pptn. (Et2O addn.), washing (Et2O), drying; elem. anal.;

upstream raw materials:

[tris(μ-chloro)bis((triphos)ruthenium(II))] chloride

silver trifluoromethanesulfonate

dimethyl sulfoxide

[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

Downstream raw materials:

Ru(CF₃SO₃)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)⁽¹⁺⁾*CF₃SO₃^(1-)={Ru(CF₃SO₃)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)}(CF₃SO₃)

dimethyl sulfoxide