Chemical Property of (1R)-(-)-Camphorquinone
Chemical Property:
- Vapor Pressure:0.0817mmHg at 25°C
- Melting Point:200-203 °C(lit.)
- Refractive Index:1.5
- Boiling Point:226.473 °C at 760 mmHg
- Flash Point:82.965 °C
- PSA：34.14000
- Density:1.098 g/cm3
- LogP:1.58070
- Storage Temp.:Store below +30°C.
- Solubility.:almost transparency in Methanol
- XLogP3:1.5
- Hydrogen Bond Donor Count:0
- Hydrogen Bond Acceptor Count:2
- Rotatable Bond Count:0
- Exact Mass:166.099379685
- Heavy Atom Count:12
- Complexity:278
- Purity/Quality:
-
98%,99%, *data from raw suppliers
(1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione *data from reagent suppliers
Safty Information:
- Pictogram(s):
Xn
- Hazard Codes:Xn
- Statements:
22-43
- Safety Statements:
36/37
- MSDS Files:
-
SDS file from LookChem
Useful:
- Canonical SMILES:CC1(C2CCC1(C(=O)C2=O)C)C
- Isomeric SMILES:C[C@@]12CC[C@@H](C1(C)C)C(=O)C2=O
-
Uses
(1R)-(-)Camphorquinone are used as visible light photoinitiator for biomedical applications such as in dental surgery. (1R)-(?)-Camphorquinone can be used as a chiral starting material for the preparation of: α-Hydroxycamphors by selective reduction of keto groups using various vegetables. Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies. Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents. Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement. (1R)-(-)-Camphorquinone may be used as an analytical standard for the determination of the analyte in dental resin composite restorations in the oral environment in contact with food and beverages, and biological samples by analytical techniques.
