(2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

Base Information

Chemical Name:(2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate
CAS No.:1353637-77-0
Molecular Formula:C₂₀H₃₀O₆Si
Molecular Weight:394.54
Hs Code.:

Synonyms:(2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

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Chemical Property of (2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

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Technology Process of (2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

There total 2 articles about (2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: ethyl 3-dimethylphenylsilyl-2-ethoxycarbonyl-4-formylhexanoate

: 1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

: 1353637-77-0
(2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

Guidance literature:: With sodium phosphate dibasic dihydrate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; for 4h; optical yield given as %de;
DOI:10.1016/j.tetasy.2011.10.013

Reference yield:

: 130247-53-9
ethyl 2-ethoxycarbonyl-3-dimethyl(phenyl)silyl-2-propenoate

: 1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

: 1353637-77-0
(2S,3R)-1,1-di(ethoxycarbonyl)-2-dimethyl(phenyl)-silylpentan-3-yl formate

Guidance literature:: Multi-step reaction with 2 steps

1: (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; acetic acid / dichloromethane / 96 h / 0 - 28 °C

2: sodium phosphate dibasic dihydrate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 4 h / 0 - 20 °C

With (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; sodium phosphate dibasic dihydrate; acetic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 1: Michael addition / 2: Baeyer-Villiger oxidation;
DOI:10.1016/j.tetasy.2011.10.013