[Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)]

Base Information

• Chemical Name: [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)]
• CAS No.: 1616704-01-8
• Molecular Formula: C₂₇H₃₄Cl₂N₂Se
• Molecular Weight: 536.446
• Mol file: 1616704-01-8.mol

Synonyms:[Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)]

Chemical Property of [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)]

There total 2 articles about [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[1,3-bis(2,6-diisopropylphenyl)-4,5-dichloro]imidazolium chloride (905931-87-5) → [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)] (1616704-01-8)

Guidance literature:

With selenium; triethylamine; In acetone; at 60 ℃; for 16h; Reagent/catalyst;

DOI:10.1039/d0dt02558e

Reference yield: 76.0%

selenium (7782-49-2) + 1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene → [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)] (1616704-01-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃; Inert atmosphere; Glovebox;

DOI:10.1021/om500610w

Reference yield: 100.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)] (1616704-01-8) → [AuCl(Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene))]

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1021/om500610w

upstream raw materials:

selenium

[1,3-bis(2,6-diisopropylphenyl)-4,5-dichloro]imidazolium chloride