4-Hydrazino-2,6-dimethylpyrimidine

Base Information

• Chemical Name: 4-Hydrazino-2,6-dimethylpyrimidine
• CAS No.: 14331-56-7
• Molecular Formula: C6H10N4
• Molecular Weight: 138.172
• Hs Code.: 2933990090
• European Community (EC) Number: 691-362-4
• DSSTox Substance ID: DTXSID70353015
• Nikkaji Number: J809.882D
• Wikidata: Q82130463
• Mol file: 14331-56-7.mol

Synonyms:14331-56-7;4-hydrazino-2,6-dimethylpyrimidine;4-Hydrazinyl-2,6-Dimethylpyrimidine;2,6-Dimethyl-4-hydrazinopyrimidine;(2,6-dimethylpyrimidin-4-yl)hydrazine;(2,6-Dimethyl-pyrimidin-4-yl)-hydrazine;MFCD00102150;Pyrimidine,4-hydrazinyl-2,6-dimethyl-;4(1H)-Pyrimidinone, 2,6-dimethyl-, hydrazone;SCHEMBL2722102;DTXSID70353015;HVAYIAWJHRUOBC-UHFFFAOYSA-N;2,4-dimethyl-6-hydra-zinopyrimidine;AKOS000279932;PS-4202;SB33624;BB 0216532;CS-0216188;FT-0618595;EN300-36015;AC-907/25014145;J-515456

Chemical Property of 4-Hydrazino-2,6-dimethylpyrimidine

Chemical Property:

• Vapor Pressure: 0.0707mmHg at 25°C
• Melting Point: 182-184°C
• Refractive Index: 1.524
• Boiling Point: 282.4 °C at 760 mmHg
• Flash Point: 124.6 °C
• PSA: 63.83000
• Density: 1.2 g/cm³
• LogP: 1.15230
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 138.090546336
• Heavy Atom Count: 10
• Complexity: 106

Purity/Quality:

97% ^*data from raw suppliers

4-Hydrazinyl-2,6-dimethylpyrimidine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=NC(=N1)C)NN

Technology Process of 4-Hydrazino-2,6-dimethylpyrimidine

There total 3 articles about 4-Hydrazino-2,6-dimethylpyrimidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1-(4-Chloro-phenyl)-ethanone O-(2,6-dimethyl-pyrimidin-4-yl)-oxime (128381-47-5) → 4-hydrazinyl-2,6-dimethylpyrimidine (14331-56-7) + 4-chloroacetophenone oxime (1956-39-4)

Guidance literature:

With hydrazine hydrate; In ethanol; for 6h; Heating;

DOI:10.1007/BF00473866

Reference yield: 82.0%

4-chloro-2,6-dimethylpyrimidine (4472-45-1) → 4-hydrazinyl-2,6-dimethylpyrimidine (14331-56-7)

Guidance literature:

With hydrazine hydrate; In various solvent(s); for 1h; Ambient temperature;

Reference yield:

→ 4-hydrazinyl-2,6-dimethylpyrimidine (14331-56-7)

Guidance literature:

DOI:10.1039/P19720000522 DOI:10.1039/jr9630005642 DOI:10.1016/S0040-4020(01)93149-7

upstream raw materials:

4-chloro-2,6-dimethylpyrimidine

1-(4-Chloro-phenyl)-ethanone O-(2,6-dimethyl-pyrimidin-4-yl)-oxime

Downstream raw materials:

C₁₄H₁₆N₄O₂

C₁₄H₁₆N₄

C₁₃H₁₃FN₄

C₁₃H₁₃ClN₄