(CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2

Base Information

Chemical Name:(CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2
CAS No.:956029-32-6
Molecular Formula:C₄₇H₅₂Fe₂Si₃
Molecular Weight:812.88
Hs Code.:

Synonyms:(CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2

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Chemical Property of (CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2

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Technology Process of (CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2

There total 1 articles about (CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 956029-31-5
PhClSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2

: 1730-25-2
allylmagnesium bromide

: 956029-32-6
(CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2

Guidance literature:: In diethyl ether; (Ar); std. Schlenk technique; soln. of Fe complex in Et2O was added dropwise with stirring to soln. of Mg compd. in Et2O; refluxed for 4 h; cooled to 0°C; aq. NH4Cl added; org. layer septd.; washed (H2O); dried (MgSO4); solvent removed (vac.); chromd. (silica gel, hexane); solvent removed (vac.); elem. anal.;
DOI:10.1021/om700559t

Reference yield: 60.0%

: 956029-32-6
(CH2=CHCH2)PhSi[(CH2)2MePhSi(η5-C5H4)Fe(η5-C5H5)]2

: 1-dimethylsilanyl-3-[tris-(3-dimethylsilanyl-propyl)-silanyl]-propane

: Si(C₃H₆Si(CH₃)2C₃H₆Si(C₆H₅)(C₂H₄Si(CH₃)(C₆H₅)(C₅H₄))2)4^(8-)*8Fe⁽²⁺⁾*8C₅H₅^(1-)=C₂₀₈H₂₆₀Si₁₇Fe₈

Guidance literature:: platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane; In toluene; (Ar); std. Schlenk technique; Pt catalyst was added to soln. of Fe complex in toluene; mixt. was stirred at room temp. for 0.5 h; soln. of silane in toluene was added dropwise; heated at 65°C for 12 h; IR and NMR monitoring; filtered; chromd. (silica gel, hexane); elem. anal.;
DOI:10.1021/om700559t