(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

Base Information

• Chemical Name: (5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride
• CAS No.: 323196-43-6
• Molecular Formula: C₁₃H₁₈N₂O*ClH
• Molecular Weight: 254.76
• Hs Code.: 2933990090
• European Community (EC) Number: 625-207-9
• Mol file: 323196-43-6.mol

Synonyms:323196-43-6;(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride;(R)-5-Benzyl-2,2,3-trimethylimidazolidin-4-one hydrochloride;(5R)-2,2,3-Trimethyl-5-phenylmethyl-4-imidazolidinone monohydrochloride;(5R)-5-benzyl-2,2,3-trimethylimidazolidin-4-one;hydrochloride;SCHEMBL3191316;(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone hydrochloride;MFCD08276839;AKOS015901364;BS-16866;D82970;J-018704;(R)-5-Benzyl-2,2,3-trimethylimidazolidin-4-one HCl;(R)-5-Benzyl-2,2,3-trimethylimidazolidin-4-onehydrochloride;(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride, 97%

Chemical Property of (5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

Chemical Property:

• Vapor Pressure: 4.24E-05mmHg at 25°C
• Melting Point: 157-161 °C
• Boiling Point: 351 °C at 760 mmHg
• Flash Point: 166.1 °C
• PSA: 32.34000
• LogP: 2.46410
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 254.1185909
• Heavy Atom Count: 17
• Complexity: 269

Purity/Quality:

98%,99%, ^*data from raw suppliers

(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(NC(C(=O)N1C)CC2=CC=CC=C2)C.Cl
• Isomeric SMILES: CC1(N[C@@H](C(=O)N1C)CC2=CC=CC=C2)C.Cl
• Uses: Used in first highly enantioselective organocatalytic Diels-Alder reaction and 1,3-dipolar addition.

Technology Process of (5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

There total 1 articles about (5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-1-(methylaminocarbonyl)-3-phenylpropanaminium chloride (111321-55-2) + acetone (67-64-1) → (5R)-5-benzyl-2,2,3-trimethyl-4-oxoimidazolidin-1-ium chloride (323196-43-6,278173-23-2)

Guidance literature:

With toluene-4-sulfonic acid; In methanol; Heating;

DOI:10.1107/S0108270107051396

upstream raw materials:

(R)-1-(methylaminocarbonyl)-3-phenylpropanaminium chloride

acetone

Refernces