N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride

Base Information

• Chemical Name: N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride
• CAS No.: 83706-29-0
• Molecular Formula: C₁₃H₁₂FNO₂S
• Molecular Weight: 265.308
• Mol file: 83706-29-0.mol

Synonyms:N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride

Chemical Property of N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride

There total 4 articles about N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(4-methoxyphenyl)sulfurimidoyl difluoride + phenyllithium (591-51-5) → N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride (83706-29-0)

Guidance literature:

In dibutyl ether; at -78 ℃; for 0.0833333h; Sealed tube; Inert atmosphere;

DOI:10.1002/anie.201712145

Reference yield: 70.0%

→ N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride (83706-29-0)

Guidance literature:

at -78 ℃; for 0.0833333h; Inert atmosphere;

Reference yield:

4-methoxy-aniline (104-94-9) → N-(4-Methoxyphenyl)benzenesulfonimidoyl fluoride (83706-29-0)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine; thionyl tetrafluoride / acetonitrile / 0.5 h / 20 °C / Sealed tube

2: dibutyl ether / 0.08 h / -78 °C / Sealed tube; Inert atmosphere

With thionyl tetrafluoride; triethylamine; In dibutyl ether; acetonitrile;

DOI:10.1002/anie.201712145

upstream raw materials:

N-(4-methoxyphenyl)benzenesulfinamide

phenyllithium

4-methoxy-aniline

Downstream raw materials:

(±)-((4-methoxyphenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone