p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Base Information

Chemical Name:p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside
CAS No.:889453-93-4
Molecular Formula:C₂₈H₂₅NO₈
Molecular Weight:503.508
Hs Code.:

Synonyms:p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Suppliers and Price of p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Chemical Property:

Purity/Quality:: 97% ^*data from raw suppliers

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Technology Process of p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

There total 4 articles about p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1125-88-8
benzaldehyde dimethyl acetal

: 138906-41-9
4-methoxylphenzyl 2-deoxy-2-phthalimido-3,4,6-tri-O-acetyl-β-D-glucopyranoside

: 889453-93-4
p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: 4-methoxylphenzyl 2-deoxy-2-phthalimido-3,4,6-tri-O-acetyl-β-D-glucopyranoside; With sodium methylate; In methanol; N,N-dimethyl-formamide; at 20 ℃; for 0.5h;

benzaldehyde dimethyl acetal; With camphor-10-sulfonic acid; In acetonitrile; at 80 ℃; for 0.5h; pH=2;
DOI:10.1055/s-0037-1609719

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 138906-42-0
p-Methoxyphenyl 2-deoxy-2-phthalimido-β-D-glucopyranoside

: 889453-93-4
p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: With p-toluenesulfonic acid monohydrate; In N,N-dimethyl-formamide; at 40 ℃; for 6h; under 750.075 Torr;
DOI:10.1016/j.carres.2010.01.002

Reference yield:

: 10022-13-6
1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose

: 889453-93-4
p-methoxyphenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: boron trifluoride diethyl etherate / 1,2-dichloro-ethane / 3.5 h / 0 - 50 °C / Molecular sieve; Inert atmosphere

2.1: sodium methylate / N,N-dimethyl-formamide; methanol / 0.5 h / 20 °C

2.2: 0.5 h / 80 °C / pH 2

With boron trifluoride diethyl etherate; sodium methylate; In methanol; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1055/s-0037-1609719