1-pentyl-1-heptenyldiphenylphosphane

Base Information

• Chemical Name: 1-pentyl-1-heptenyldiphenylphosphane
• CAS No.: 855516-19-7
• Molecular Formula: C₂₄H₃₃P
• Molecular Weight: 352.5
• Mol file: 855516-19-7.mol

Synonyms:1-pentyl-1-heptenyldiphenylphosphane

Chemical Property of 1-pentyl-1-heptenyldiphenylphosphane

Chemical Property:

Purity/Quality:

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Technology Process of 1-pentyl-1-heptenyldiphenylphosphane

There total 2 articles about 1-pentyl-1-heptenyldiphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

6-dodecyne (6975-99-1) + diphenylphosphane (829-85-6) → 1-pentyl-1-heptenyldiphenylphosphane (855516-19-7)

Guidance literature:

With n-butyllithium; cobalt acetylacetonate; In tetrahydrofuran; 1,4-dioxane; hexane; for 2h; Heating;

DOI:10.1002/anie.200500255

Reference yield: 67.0%

6-dodecyne (6975-99-1) + (tert-butyldimethylsilyl)diphenylphosphine (678187-53-6) → 1-pentyl-1-heptenyldiphenylphosphane (855516-19-7)

Guidance literature:

With silver trifluoromethanesulfonate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; In methanol; benzene; Heating;

DOI:10.1021/jo061739f

Reference yield:

1-pentyl-1-heptenyldiphenylphosphane (855516-19-7) → (E)-6-diphenylthiophosphinyl-6-dodecene

Guidance literature:

With sulfur; water; cobalt acetylacetonate; In tetrahydrofuran; 1,4-dioxane; hexane; at 20 ℃; for 0.25h;

DOI:10.1002/anie.200500255

upstream raw materials:

6-dodecyne

diphenylphosphane

(tert-butyldimethylsilyl)diphenylphosphine