RhH₃(triars)

Base Information

• Chemical Name: RhH₃(triars)
• CAS No.: 118473-83-9
• Molecular Formula: C₄₁H₄₂As₃Rh
• Molecular Weight: 862.455
• Mol file: 118473-83-9.mol

Synonyms:RhH₃(triars)

Chemical Property of RhH₃(triars)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RhH₃(triars)

There total 2 articles about RhH₃(triars) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

sodium tetrahydroborate (16940-66-2) + RhCl3(triars) (118473-81-7) → RhH3(triars) (118473-83-9)

Guidance literature:

In ethanol; N2 atmosphere; addn. of NaBH4 to suspn. of Rh-complex, stirring (0°C, 15 min), warming to room temp. (15 min), refluxing (20 min); pptn. on cooling (ice bath), collection (filtration), washing (EtOH), drying (vac), recrystn. (CH2Cl2/EtOH);

DOI:10.1021/ja00188a027

Reference yield:

triars (40169-66-2) → RhH3(triars) (118473-83-9)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanol

2: ethanol

In ethanol;

DOI:10.1021/ja00188a027

Reference yield: 62.0%

thallium(I) hexafluorophosphate (60969-19-9) + (triphenylarsine)gold(I) chloride (25749-29-5) + RhH3(triars) (118473-83-9) → {RhAu3H3(AsPh3)3(triars)}{PF6}2 (118494-02-3)

Guidance literature:

In tetrahydrofuran; dichloromethane; N2 atmosphere; addn. of TlPF6 in THF to soln. of Rh- and of Au-complexes (molar ratio 1:3) in CH2Cl2, stirring (15 min); evapn., suspn. (CH2Cl2), filtration (celite), recrystn. (CH2Cl2/MeOH, -20°C), washing (MeOH, ether); elem. anal.;

DOI:10.1021/ja00188a027

upstream raw materials:

sodium tetrahydroborate

RhCl₃(triars)

triars

Downstream raw materials:

{RhAu₃H₂(AsPh₃)3(triars)}{CF₃SO₃}2

{RhAu₃H₃(AsPh₃)3(triars)}{PF₆}2