{Pt(SeC₆H₅)2(CH₂(CH₂P(C₆H₅)2)2)}

Base Information

• Chemical Name: {Pt(SeC₆H₅)2(CH₂(CH₂P(C₆H₅)2)2)}
• CAS No.: 80462-61-9
• Molecular Formula: C₃₉H₃₆P₂PtSe₂
• Molecular Weight: 919.662
• Mol file: 80462-61-9.mol

Synonyms:{Pt(SeC₆H₅)2(CH₂(CH₂P(C₆H₅)2)2)}

Chemical Property of {Pt(SeC₆H₅)2(CH₂(CH₂P(C₆H₅)2)2)}

Chemical Property:

Purity/Quality:

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Technology Process of {Pt(SeC₆H₅)2(CH₂(CH₂P(C₆H₅)2)2)}

There total 2 articles about {Pt(SeC₆H₅)2(CH₂(CH₂P(C₆H₅)2)2)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) + diphenyl diselenide (1666-13-3) → {Pt(SeC6H5)2(CH2(CH2P(C6H5)2)2)} (80462-61-9)

Guidance literature:

With sodium tetrahydroborate; In ethanol; dichloromethane; soln. preparated from Ph2Se2 and NaBH4 in EtOH added to stirred slurry PtCl2(dppp) in CH2Cl2; after 2 min mixt. filtered, residue extd. with 95% EtOH and concd., ppt. washed with H2O, EtOH, Et2O and recrystd. from CH2Cl2 by adding 95% EtOH; elem. anal.;

DOI:10.1021/ja00369a024

Reference yield: 68.0%

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) + sodium phenylselenide (23974-72-3) → {Pt(SeC6H5)2(CH2(CH2P(C6H5)2)2)} (80462-61-9)

Guidance literature:

In benzene; addn. of Se compd. in one portion to Pt complex suspension under N2; stirring, room temp., 5h; evapn.; extn. (CH2Cl2); crystn.; filtration; washing (methanol); drying; elem. anal.;

DOI:10.1039/DT9930001509

upstream raw materials:

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

sodium phenylselenide

diphenyl diselenide