ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

Base Information

Chemical Name:ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate
CAS No.:94799-93-6
Molecular Formula:C₂₆H₃₈O₈Si
Molecular Weight:506.668
Hs Code.:

Synonyms:ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

Suppliers and Price of ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

There total 4 articles about ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 94744-82-8
3-O-benzoyl-1,2-O-isopropylidene-6-O-(tert-butyldimethylsilyl)-α-D-xylo-hexofuran-5-ulose

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: 94799-93-6
ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

: 94799-92-5
ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(Z)-enofuranuronate

Guidance literature:: In acetonitrile; for 2h; Heating;
DOI:10.1021/jo00350a062

Reference yield:

: 22529-61-9
(1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol

: 94799-93-6
ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / pyridine / 1 h

2: 1.) CrO₃, pyridine, 2.) Ac₂O / 1.) CH₂Cl₂, 5 min, 2.) CH₂Cl₂, 1 h

3: 9 percent / acetonitrile / 2 h / Heating

With pyridine; chromium(VI) oxide; acetic anhydride; In acetonitrile;
DOI:10.1021/jo00350a062

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 94799-93-6
ethyl 3-O-benzoyl-5-C-<<(tert-butyldimethylsilyl)oxy>methyl>-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hept-5(E)-enofuranuronate

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / pyridine / 1 h

2: 1.) CrO₃, pyridine, 2.) Ac₂O / 1.) CH₂Cl₂, 5 min, 2.) CH₂Cl₂, 1 h

3: 9 percent / acetonitrile / 2 h / Heating

With pyridine; chromium(VI) oxide; acetic anhydride; In acetonitrile;
DOI:10.1021/jo00350a062