o-(trimethylsilyl)phenyllithium

Base Information

• Chemical Name: o-(trimethylsilyl)phenyllithium
• CAS No.: 154318-23-7
• Molecular Formula: C₉H₁₃LiSi
• Molecular Weight: 156.229
• Mol file: 154318-23-7.mol

Synonyms:o-(trimethylsilyl)phenyllithium

Chemical Property of o-(trimethylsilyl)phenyllithium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of o-(trimethylsilyl)phenyllithium

There total 1 articles about o-(trimethylsilyl)phenyllithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

m-chlorophenyltrimethylsilane (4405-42-9) + lithium (7439-93-2) → o-(trimethylsilyl)phenyllithium (154318-23-7)

Guidance literature:

In not given;

DOI:10.1021/ja01114a041 DOI:10.1021/ja01152a070 DOI:10.1021/ja01108a009 DOI:10.1021/ja01176a101

Reference yield: 93.0%

o-(trimethylsilyl)phenyllithium (154318-23-7) + diphenyl acetylene (501-65-5) → 1,1-dimethyl-2,3-diphenyl-1H-benzo[b]silole (1016642-73-1)

Guidance literature:

o-(trimethylsilyl)phenyllithium; diphenyl acetylene; With iron(III)-acetylacetonate; In diethyl ether; at -20 ℃; for 2.5h; Inert atmosphere;

With methanol; In diethyl ether; for 0.0833333h; Inert atmosphere;

DOI:10.1039/c1cc11989c

Reference yield: 47.0%

o-(trimethylsilyl)phenyllithium (154318-23-7) → 3-trimethylsilylbenzoic acid (15290-28-5)

Guidance literature:

With CO₂; In not given; (CH3)3SiC6H4Li and solid CO2; hydrolysis;;

DOI:10.1021/ja01106a043 DOI:10.1021/ja01176a101

upstream raw materials:

m-chlorophenyltrimethylsilane

lithium

Downstream raw materials:

3-trimethylsilylbenzoic acid

1,1,3-trimethyl-2-phenyl-1H-benzo[b]silole

1,1,2-trimethyl-3-phenyl-1H-benzo[b]silole

2-butyl-1,1-dimethyl-3-phenyl-1H-benzo[b]silole