L-iditol hexaacetate

Base Information

• Chemical Name: L-iditol hexaacetate
• CAS No.: 13443-46-4
• Molecular Formula: C₁₈H₂₆O₁₂
• Molecular Weight: 434.397
• Mol file: 13443-46-4.mol

Synonyms:L-iditol hexaacetate

Chemical Property of L-iditol hexaacetate

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 114-119°C
• Solubility.: Chloroform, Ethyl Acetate, Methanol

Purity/Quality:

98% ^*data from raw suppliers

L-IditolHexaacetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: L-Iditol Hexaacetate (cas# 13443-46-4) is a compound useful in organic synthesis.

Technology Process of L-iditol hexaacetate

There total 23 articles about L-iditol hexaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.3%

D-glucitol pentaacetate (80832-30-0,80876-60-4) + L-iditol pentaacetate (80832-30-0) → L-iditol hexaacetate (13443-46-4,5346-76-9) + 1,2,3,4,5,6-hexa-O-acetyl-D-glucitol (7208-47-1,5346-76-9)

Guidance literature:

With sodium acetate; In acetic anhydride;

DOI:10.1016/S0008-6215(00)80972-6

Reference yield: 47.0%

L-sorbose (35673-97-3) + acetic anhydride (108-24-7) → L-iditol hexaacetate (13443-46-4,5346-76-9) + 1,2,3,4,5,6-hexa-O-acetyl-D-glucitol (7208-47-1,5346-76-9)

Guidance literature:

L-sorbose; With sodium tetrahydroborate; In methanol; water; at 20 ℃; for 1.5h;

acetic anhydride; In pyridine; at 50 ℃;

DOI:10.1016/S0040-4020(00)00220-9

Reference yield:

L-sorbose (87-79-6,18875-34-8) → L-iditol hexaacetate (13443-46-4,5346-76-9) + 1,2,3,4,5,6-hexa-O-acetyl-D-glucitol (7208-47-1,5346-76-9)

Guidance literature:

With water; nickel; at 100 ℃; under 97822.5 Torr; Hydrogenation_.Acetylieren mit Eisessig und Natriumacetat auf dem Dampfbad;

DOI:10.1039/jr9440000364 DOI:10.1002/hlca.19460290120

upstream raw materials:

L-sorbose

L-iditol

acetic anhydride

D-glucitol pentaacetate

Downstream raw materials:

DL-iditol hexa-acetate

2,4:3,5-di-O-methylene-L-iditol

S,R-4,4'-bi-(2,2-dimethyl-5-p-tolylsulphonylmethyldioxolanyl)

C₂₆H₃₀O₈

Refernces

• 1、 Jones,Wiggins. "-". . p. 364. Retrieved 1944.
• 2、 Tindall, Daniel J.,Mader, Steffen,Kindler, Alois,Rominger, Frank,Hashmi, A. Stephen K.,Schaub, Thomas. "Selective and Scalable Synthesis of Sugar Alcohols by Homogeneous Asymmetric Hydrogenation of Unprotected Ketoses". supporting information. p. 721 - 725. Retrieved 2020/10/19.
• 3、 Akgul, Yurdanur,Aktas, Lale Yildiz,Anil, Huseyin. "Compounds from flowers of Daucus carota L. SSp. carota and their antioxidant activity". experimental part. p. 889 - 892. Retrieved 2010/08/06.