phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

Base Information

Chemical Name:phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester
CAS No.:725739-83-3
Molecular Formula:C₁₂H₂₂IO₄P
Molecular Weight:388.183
Hs Code.:

Synonyms:phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

Suppliers and Price of phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

There total 3 articles about phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 814-49-3
diethyl chlorophosphate

: 341497-26-5
(R)-4,4-dimethyl-2-iodo-2-cyclohexen-1-ol

: 725739-83-3
phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

Guidance literature:: With 1-methyl-1H-imidazole; In diethyl ether; at 20 ℃; for 16h;
DOI:10.1021/ol049221q

Reference yield:

: 1073-13-8
4,4-dimethylcyclohexenone

: 725739-83-3
phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / PDC; I₂ / CH₂Cl₂ / 51 h / 20 °C

2: 90 percent / L-diphenylprolinol; B(OMe)3; borane-N,N-diethylaniline complex / tetrahydrofuran / 1 h / 20 °C

3: 85 percent / N-methylimidazole / diethyl ether / 16 h / 20 °C

With 1-methyl-1H-imidazole; dipyridinium dichromate; borane N,N-diethylaniline complex; (R)-diphenylprolinol; Trimethyl borate; iodine; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol049221q

Reference yield:

: 157952-85-7
2-iodo-4,4-dimethyl-cyclohex-2-enone

: 725739-83-3
phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / L-diphenylprolinol; B(OMe)3; borane-N,N-diethylaniline complex / tetrahydrofuran / 1 h / 20 °C

2: 85 percent / N-methylimidazole / diethyl ether / 16 h / 20 °C

With 1-methyl-1H-imidazole; borane N,N-diethylaniline complex; (R)-diphenylprolinol; Trimethyl borate; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ol049221q