Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol

Base Information

Chemical Name:Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol
CAS No.:219969-03-6
Molecular Formula:C₆₇H₆₄O₉S₂
Molecular Weight:1077.37
Hs Code.:

Synonyms:Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol

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Technology Process of Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol

There total 6 articles about Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 219969-01-4
Bis-[(4S,5S,6R)-3-((R)-benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-methanol

: 219969-03-6
Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol

Guidance literature:: With sodium cyanoborohydride; acetic acid; 1.) r.t., 10 h, 2.) 50 deg C, 4 h;
DOI:10.1055/s-1998-4503

Reference yield: 86.0%

: 219969-02-5
Bis-[(4S,5S,6R)-3-((S)-benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-methanol

: 219969-03-6
Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol

Guidance literature:: With sodium cyanoborohydride; acetic acid; 1.) r.t., 10 h, 2.) 50 deg C, 4 h;
DOI:10.1055/s-1998-4503

Reference yield:

: 125710-64-7
1,5-anhydro-3,4,6-tri-O-benzyl-1,2-dideoxy-2-((S)-phenylsulfinyl)-D-lyxo-hex-1-enitol

: 219969-03-6
Bis-((4S,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylsulfanyl-5,6-dihydro-4H-pyran-2-yl)-methanol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LDA / 1.) THF, HMPA, -100 deg C, 1.5 h, 2.) THF, HMPA, -100 deg C, 2 h

2: 86 percent / NaCNBH₃, HOAc / 1.) r.t., 10 h, 2.) 50 deg C, 4 h

With sodium cyanoborohydride; acetic acid; lithium diisopropyl amide;
DOI:10.1055/s-1998-4503