glucal epoxide

Base Information

Chemical Name:glucal epoxide
CAS No.:1011723-04-8
Molecular Formula:C₂₇H₂₈O₅
Molecular Weight:432.516
Hs Code.:

Synonyms:glucal epoxide

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Chemical Property of glucal epoxide

Chemical Property:

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Technology Process of glucal epoxide

There total 7 articles about glucal epoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₂H₃₆BNO₈

: 1011723-04-8
glucal epoxide

Guidance literature:: Multi-step reaction with 3 steps

1: methanol / 18 h / 70 °C

2: sodium carbonate; (1,2-dimethoxyethane)dichloronickel(II); 4,4'-di-tert-butyl-2,2'-bipyridine; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate / 1,4-dioxane / 24 h / 23 °C / Inert atmosphere; Irradiation

3: sodium hydrogencarbonate; oxone||potassium monopersulfate triple salt / dichloromethane; acetone; water / 3 h / 0 - 23 °C

With (1,2-dimethoxyethane)dichloronickel(II); oxone||potassium monopersulfate triple salt; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; sodium hydrogencarbonate; sodium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine; In 1,4-dioxane; methanol; dichloromethane; water; acetone;
DOI:10.1021/acs.orglett.1c01035

Reference yield:

: C₂₇H₃₁BO₆

: 1011723-04-8
glucal epoxide

Guidance literature:: Multi-step reaction with 4 steps

1: toluene; dimethyl sulfoxide / 3 h / 115 °C

2: methanol / 18 h / 70 °C

3: sodium carbonate; (1,2-dimethoxyethane)dichloronickel(II); 4,4'-di-tert-butyl-2,2'-bipyridine; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate / 1,4-dioxane / 24 h / 23 °C / Inert atmosphere; Irradiation

4: sodium hydrogencarbonate; oxone||potassium monopersulfate triple salt / dichloromethane; acetone; water / 3 h / 0 - 23 °C

With (1,2-dimethoxyethane)dichloronickel(II); oxone||potassium monopersulfate triple salt; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; sodium hydrogencarbonate; sodium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine; In 1,4-dioxane; methanol; dichloromethane; water; dimethyl sulfoxide; acetone; toluene;
DOI:10.1021/acs.orglett.1c01035

Reference yield:

: potassium 1-(3,4,6-tri-O-benzyl-1,2-dideoxy-α-D-glucopyranosyl)trifluoroborate

: 1011723-04-8
glucal epoxide

Guidance literature:: Multi-step reaction with 2 steps

1: sodium carbonate; (1,2-dimethoxyethane)dichloronickel(II); 4,4'-di-tert-butyl-2,2'-bipyridine; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate / 1,4-dioxane / 24 h / 23 °C / Inert atmosphere; Irradiation

2: sodium hydrogencarbonate; oxone||potassium monopersulfate triple salt / dichloromethane; acetone; water / 3 h / 0 - 23 °C

With (1,2-dimethoxyethane)dichloronickel(II); oxone||potassium monopersulfate triple salt; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; sodium hydrogencarbonate; sodium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine; In 1,4-dioxane; dichloromethane; water; acetone;
DOI:10.1021/acs.orglett.1c01035