[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)]

Base Information

Chemical Name:[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)]
CAS No.:479041-92-4
Molecular Formula:C₄₄H₄₃NO₂P₂Ru
Molecular Weight:780.848
Hs Code.:

Synonyms:[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)]

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Chemical Property of [(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)]

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Technology Process of [(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)]

There total 3 articles about [(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: pentamethylcyclopentadienyl(1,2-bis(diphenylphosphino)ethane)chlororuthenium(II)

: 3109-63-5
tert-butylammonium hexafluorophosphate(V)

: 75867-38-8
4-nitro-1-(trimethylsilylethynyl)benzene

: 479041-92-4
[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)]

Guidance literature:: With potassium tert-butoxide; In methanol; (inert atm., Schlenk) Ru-complex, PF6-compound, alkyne were introduced under Ar in a flask, methanol was added, the mixt. refluxed for 20 h, evacuated, potassium tert-butoxide and methanol were added, stirred for 12 h at ambient temp.; ppt. was filtered on a frit, washed with methanol, dried in vac.;
DOI:10.1021/om050799t

Reference yield: 20.0%

: 583884-57-5
(pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)RuC₂H

: 586-78-7
para-nitrophenyl bromide

: 479041-92-4
[(η5-C5Me5)(η2-dppe)Ru(C2-1,4-(C6H4)NO2)]

Guidance literature:: With (P(C₆H₅)3)2PdCl₂; CuI; In further solvent(s); (inert atm., Schlenk) Ru-complex, Pd-complex and CuI were introduced in a Schlenk flask under Ar, bromide was added into HN(CH(CH3)2)2, the mixt. was refluxed for 12 h; the solvent was cryogenically trapped, the residue was extd. with toluene, filtered, evapd., eluted through a neutral alumina column using an n-pentane/diethyl ether gradient followed by repeated methanol washing, dried in vac.; elem. anal.;
DOI:10.1021/om050799t