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Tetrabutylammonium hexafluorophosphate Manufacturer/High quality/Best price/In stock
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TetrabutylaMMoniuM Hexafluorophosphate
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2-(5-amino-3-pyrimido[5,4-e][1,2,4]triazinyl)acetamide
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Tetrabutylammonium hexafluorophosphate
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3109-63-5 Tetrabutylammonium hexafluorophosphate
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3109-63-5 Usage

Chemical Properties

off-white powder

Purification Methods

Recrystallise it from saturated EtOH/water and dry it for 10hours in a vacuum at 70o. Also recrystallise it three times from absolute EtOH and dry it for 2 days in a drying pistol under a vacuum at boiling toluene temperature [Bedard & Dahl J Am Chem Soc 108 5933 1986]. It is a stable supporting electrolyte in organic solvents [Baiser in Organic Electrochemitry M. Dekker NY p228 1973.]
InChI:InChI=1/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1

3109-63-5 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (T1279)  Tetrabutylammonium Hexafluorophosphate  >98.0%(T) 3109-63-5 25g 595.00CNY Detail
TCI America (T1279)  Tetrabutylammonium Hexafluorophosphate  >98.0%(T) 3109-63-5 250g 2,800.00CNY Detail
Alfa Aesar (A17196)  Tetra-n-butylammonium hexafluorophosphate, 98%    3109-63-5 25g 575.0CNY Detail
Alfa Aesar (A17196)  Tetra-n-butylammonium hexafluorophosphate, 98%    3109-63-5 100g 1886.0CNY Detail
Alfa Aesar (A17196)  Tetra-n-butylammonium hexafluorophosphate, 98%    3109-63-5 500g 8165.0CNY Detail
Sigma-Aldrich (86879)  Tetrabutylammoniumhexafluorophosphate  for electrochemical analysis, ≥99.0% 3109-63-5 86879-25G 1,237.86CNY Detail
Sigma-Aldrich (86879)  Tetrabutylammoniumhexafluorophosphate  for electrochemical analysis, ≥99.0% 3109-63-5 86879-100G 4,582.89CNY Detail
Sigma-Aldrich (86874)  Tetrabutylammoniumhexafluorophosphate  purum, ≥98.0% (CHN) 3109-63-5 86874-25G 741.78CNY Detail
Sigma-Aldrich (86874)  Tetrabutylammoniumhexafluorophosphate  purum, ≥98.0% (CHN) 3109-63-5 86874-100G 2,564.64CNY Detail
Aldrich (281026)  Tetrabutylammoniumhexafluorophosphate  98% 3109-63-5 281026-5G 299.52CNY Detail
Aldrich (281026)  Tetrabutylammoniumhexafluorophosphate  98% 3109-63-5 281026-25G 679.77CNY Detail
Aldrich (281026)  Tetrabutylammoniumhexafluorophosphate  98% 3109-63-5 281026-100G 1,980.81CNY Detail

3109-63-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name tetrabutylazanium,hexafluorophosphate

1.2 Other means of identification

Product number -
Other names Tetra-n-butylammonium hexafluorophosphate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3109-63-5 SDS

3109-63-5Synthetic route

tetrabutylammomium bromide
1643-19-2

tetrabutylammomium bromide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
With trimethyl phosphite; hexafluorophosphoric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent);96%
With potassium hexafluorophosphate In dichloromethane; water at 20℃; for 24h;88%
With potassium hexafluorophosphate In dichloromethane; water at 20℃; for 24h;88%
[N(nBu)4]X; X = halide

[N(nBu)4]X; X = halide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
With silver(I) hexafluorophosphate In dichloromethane; acetonitrile at 20℃; for 10h; Darkness;92%
tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
Stage #1: phosphonic acid diethyl ester With potassium fluoride; oxalyl dichloride In acetonitrile at 20℃; Glovebox; Sealed tube; Inert atmosphere;
Stage #2: tetrabutyl-ammonium chloride In water at 20℃; for 0.166667h; Glovebox; Sealed tube; Inert atmosphere;
59%
methanol
67-56-1

methanol

C16H36N(1+)*CH4O*F6P(1-)

C16H36N(1+)*CH4O*F6P(1-)

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In dichloromethane at 26℃; Equilibrium constant; 1.3 - 1.5 M-1;
ammonium hexafluorophosphate

ammonium hexafluorophosphate

tetrabutylammomium bromide
1643-19-2

tetrabutylammomium bromide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In not given recrystn.(ethanol/water), drying (vacuo, 24 h, 80°C);
((η3-methallyl)Ni(cod))PF6

((η3-methallyl)Ni(cod))PF6

tri(3-sulfonatophenyl)phosphine tri(tetrabutylammonium)

tri(3-sulfonatophenyl)phosphine tri(tetrabutylammonium)

A

(CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3Ni(CH2C(CH3)CH2))2(C6H4SO3)(1-)

(CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3Ni(CH2C(CH3)CH2))2(C6H4SO3)(1-)

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

C

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

Conditions
ConditionsYield
In dichloromethane addn. of TPPTSNBu4 to Ni-compd. (high 2/1 ratio) in CH2Cl2, room temp.; detd. spectr.; sepn. of cod by evapn.; pptn. of NBu4PF6;
((η3-methallyl)Ni(cod))PF6

((η3-methallyl)Ni(cod))PF6

tri(3-sulfonatophenyl)phosphine tri(tetrabutylammonium)

tri(3-sulfonatophenyl)phosphine tri(tetrabutylammonium)

A

(CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3)3(3-)*2N(C4H9)4(1+)

(CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3)3(3-)*2N(C4H9)4(1+)

B

(CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3)2(C6H4SO3Ni(CH2C(CH3)CH2))(2-)*N((CH2)3CH3)4(1+)

(CH2C(CH3)CH2)Ni(C8H12)P(C6H4SO3)2(C6H4SO3Ni(CH2C(CH3)CH2))(2-)*N((CH2)3CH3)4(1+)

C

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

D

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

Conditions
ConditionsYield
In dichloromethane addn. of TPPTSNBu4 to Ni-compd. (low 2/1 ratio) in CH2Cl2, room temp.; detd. spectr.; sepn. of cod by evapn.; pptn. of NBu4PF6;
tetra(n-butyl)ammonium hydroxide
2052-49-5

tetra(n-butyl)ammonium hydroxide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
With hexafluorophosphate In water
With hexafluorophosphoric acid In water
With hexafluorophosphoric acid In water Inert atmosphere; Schlenk technique;
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In water for 24h;
ammonium hexafluorophosphate

ammonium hexafluorophosphate

tetrabutylammomium bromide
1643-19-2

tetrabutylammomium bromide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In water
hexafluorophosphoric acid

hexafluorophosphoric acid

tetra(n-butyl)ammonium hydroxide
2052-49-5

tetra(n-butyl)ammonium hydroxide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In water
tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
With hexafluorophosphoric acid; sodium hydroxide
C15H16IO3(1+)*F6P(1-)

C15H16IO3(1+)*F6P(1-)

tetrabutylammonium benzoate
18819-89-1

tetrabutylammonium benzoate

A

C25H27IO8

C25H27IO8

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
C15H16IO3(1+)*F6P(1-)

C15H16IO3(1+)*F6P(1-)

tetra-n-butylammonium p-nitrophenoxide
3002-48-0

tetra-n-butylammonium p-nitrophenoxide

A

C24H26INO9

C24H26INO9

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

C15H16IO3(1+)*F6P(1-)

C15H16IO3(1+)*F6P(1-)

A

C18H22ClIO6

C18H22ClIO6

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Thermodynamic data; Inert atmosphere;
(3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

(3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

tetrabutylammonium benzoate
18819-89-1

tetrabutylammonium benzoate

A

C21H13F6IO2

C21H13F6IO2

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
(perfluorophenyl)(phenyl)iodonium hexafluorophosphate
951037-67-5

(perfluorophenyl)(phenyl)iodonium hexafluorophosphate

tetrabutylammonium benzoate
18819-89-1

tetrabutylammonium benzoate

A

C19H10F5IO2

C19H10F5IO2

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
(3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

(3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

tetra-n-butylammonium p-nitrophenoxide
3002-48-0

tetra-n-butylammonium p-nitrophenoxide

A

C20H12F6INO3

C20H12F6INO3

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
(perfluorophenyl)(phenyl)iodonium hexafluorophosphate
951037-67-5

(perfluorophenyl)(phenyl)iodonium hexafluorophosphate

tetra-n-butylammonium p-nitrophenoxide
3002-48-0

tetra-n-butylammonium p-nitrophenoxide

A

C18H9F5INO3

C18H9F5INO3

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
(3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

(3,5-bis(trifluoromethyl)phenyl)(phenyl)iodonium hexafluorophosphate

tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

A

C14H8ClF6I

C14H8ClF6I

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Thermodynamic data; Inert atmosphere;
tetra-n-butylammonium p-nitrophenoxide
3002-48-0

tetra-n-butylammonium p-nitrophenoxide

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

A

diphenyliodonium 4-nitrophenolate

diphenyliodonium 4-nitrophenolate

B

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

triethylphosphine
554-70-1

triethylphosphine

cis-[Re(V)O(triethylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

cis-[Re(V)O(triethylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

Conditions
ConditionsYield
In ethanol; dichloromethane Re complex dissolved in ethanol, soln. of triethylphosphine in CH2Cl2 added, reflued for 1 h under N2, tetrabutylammonium hexafluorophosphate added; concd., frozen overnight, crystal collected, washed with toluene, ether;elem. anal.;99%
trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

diethyl-phenyl-phosphine
1605-53-4

diethyl-phenyl-phosphine

cis-[Re(V)O(diethylphenylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

cis-[Re(V)O(diethylphenylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

Conditions
ConditionsYield
In ethanol; dichloromethane Re complex dissolved in ethanol, soln. of diethylphenylphosphine in CH2Cl2 added, heated for 1 h under N2, tetrabutylammonium hexafluorophosphate added to warm soln.; cooled to room temp., ppt. filtered, washed with toluene, cold ethanol, ether; elem. anal.;99%
trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

trans-rhenium(V)-oxo-(Cl)(N,N'-propylenebis(acetylacetone)diimine)

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

triphenylphosphine
603-35-0

triphenylphosphine

cis-[Re(V)O(triphenylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

cis-[Re(V)O(triphenylphosphine)(N,N'-propylenebis(acetylacetonate) diimine)][PF6]

Conditions
ConditionsYield
In ethanol; dichloromethane Re complex dissolved in ethanol, soln. of triphenylphosphine in CH2Cl2 added, heated for 1 h under N2, tetrabutylammonium hexafluorophosphate added to warm soln.; cooled to room temp., ppt. filtered, washed with toluene, cold ethanol, ether; elem. anal.;99%
aqua[N,N'-ethylenebis(acetylacetone iminato)]oxotechnetium(V) bromide
87761-77-1

aqua[N,N'-ethylenebis(acetylacetone iminato)]oxotechnetium(V) bromide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

ethyl-diphenyl-phosphane
607-01-2

ethyl-diphenyl-phosphane

trans-bis(diphenylethylphosphine)(N,N'-ethylenebis(acetylacetone iminato))technetium(III) hexafluorophosphate
93427-02-2

trans-bis(diphenylethylphosphine)(N,N'-ethylenebis(acetylacetone iminato))technetium(III) hexafluorophosphate

Conditions
ConditionsYield
In methanol adding of PEtPh2 to MeOH soln. of Tc(V) complex, stirring for 15 min atroom temp., adding of Bu4NPF6; filtration, concn., cooling overnight, filtration, washing with H2O, drying in vac. over P2O5;98%
2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methyl-6-(methylthio)phenol
1186470-04-1

2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methyl-6-(methylthio)phenol

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

copper dichloride

copper dichloride

[Cu3Cl2(2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methyl-6(methylthio)phenolate)2](hexafluorphosphate)2

[Cu3Cl2(2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methyl-6(methylthio)phenolate)2](hexafluorphosphate)2

Conditions
ConditionsYield
With N(CH2CH3)3 In methanol refluxing mixt. of 2 equiv. of copper compd., 3 equiv. of phenol. deriv.and amine deriv. in methanol for 1 h, addn. of hexafluorophosphate salt; filtration, washing with cold methanol, drying in vac., elem. anal.;97%
2Os(3+)*4CH3CO2(1-)*2Cl(1-)=Os2(O2CCH3)4Cl2

2Os(3+)*4CH3CO2(1-)*2Cl(1-)=Os2(O2CCH3)4Cl2

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

(n-Bu4N)2{Os2Cl8}

(n-Bu4N)2{Os2Cl8}

Conditions
ConditionsYield
With HCl In ethanol (under N2), a sample of the Os-compound was suspended in EtOH, which had been chilled in an ice bath and saturated with gaseous HCl, mixture was refluxed for 1.5 h, treated with an EtOH soln. containing an excess of n-Bu4NPF6; removal of the solvent, resulting green oil was dissolved in CH2Cl2, addn. of ethanol, diethyl ether was carefully layered over the soln., pptn., filtn., product was washed (ethanol, diethyl ether), drying under vacuum;96%
{(triphos)Rh(μ-C2S4)Rh(triphos)}Cl2

{(triphos)Rh(μ-C2S4)Rh(triphos)}Cl2

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

{(triphos)Rh(μ-C2Se4)Rh(triphos)}(PF6)2

{(triphos)Rh(μ-C2Se4)Rh(triphos)}(PF6)2

Conditions
ConditionsYield
In dichloromethane under N2; solid (NBu4)(PF6) added to the Rh-complex in CH2Cl2; crystn. on addn. of ethanol, elem. anal.;95%
[(C41H39P3)Rh(C2S4)Rh(C41H39P3)](2+)*2Cl(1-) = [(C41H39P3)Rh(C2S4)Rh(C41H39P3)]Cl2

[(C41H39P3)Rh(C2S4)Rh(C41H39P3)](2+)*2Cl(1-) = [(C41H39P3)Rh(C2S4)Rh(C41H39P3)]Cl2

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

[(C41H39P3)Rh(C2S4)Rh(C41H39P3)](2+)*2PF6(1-)=[(C41H39P3)Rh(C2S4)Rh(C41H39P3)](PF6)2

[(C41H39P3)Rh(C2S4)Rh(C41H39P3)](2+)*2PF6(1-)=[(C41H39P3)Rh(C2S4)Rh(C41H39P3)](PF6)2

Conditions
ConditionsYield
In dichloromethane under N2; solid (NBu4)(PF6) added to the Rh-complex in CH2Cl2; crystn. on addn. of ethanol, elem. anal.;95%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

2,2'-azopyridine
2633-03-6

2,2'-azopyridine

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

[(η5-C5Me5)Ir(2,2'-azobis(pyridine))Cl]PF6
545436-48-4

[(η5-C5Me5)Ir(2,2'-azobis(pyridine))Cl]PF6

Conditions
ConditionsYield
In methanol suspn. of complex and azo compound in CH3OH stirred for 3 h, concd., treated with 3 equiv of Bu4NPF6 in methanol; ppt. filtered off, washed with methanol and diethyl ether, dried under vac.; elem. anal.;95%
di[1,4-bis(dimethylamino)-η6-benzene]chromium
639518-84-6

di[1,4-bis(dimethylamino)-η6-benzene]chromium

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

di[1,4-bis(dimethylamino)-η6-benzene]chromium hexafluorophosphate
639518-86-8

di[1,4-bis(dimethylamino)-η6-benzene]chromium hexafluorophosphate

Conditions
ConditionsYield
With 4-pyridine carbaldehyde In tetrahydrofuran a soln. of n-Bu4NPF6 added to a soln. of Cr complex, stirred for 10 min at ambient temp., 4-pyridine carbaldehyde added dropwise, stirred for 30min; pptd. (Et2O), collected, washed (Et2O, H2O), dissolved in acetone, layered with Et2O; elem. anal.;95%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

glyoxalbis(2,6-dimethylphenylimine)

glyoxalbis(2,6-dimethylphenylimine)

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

[(C5Me5)Ir(1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene)]PF6

[(C5Me5)Ir(1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene)]PF6

Conditions
ConditionsYield
In methanol stirring Ir-complex with 2.5 equiv. of diene for 4 h, pptn. on addn. of excess Bu4NCl; elem. anal.;95%
2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol
949566-81-8

2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol

water
7732-18-5

water

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

copper dichloride

copper dichloride

[CuCl(2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol)](hexafluorphosphate)*0.75water

[CuCl(2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol)](hexafluorphosphate)*0.75water

Conditions
ConditionsYield
In methanol refluxing 1:1 mixt. of copper compd. and phenol. deriv. in methanol for 1 h, addn. of hexafluorophosphate salt; filtration, washing with cold methanol, drying in vac., elem. anal.;93%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

tetra-n-butylammonium mer-tricyanido(trifluorido)phosphate

tetra-n-butylammonium mer-tricyanido(trifluorido)phosphate

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate at 25℃; for 80h; Inert atmosphere; Schlenk technique;93%
methanol
67-56-1

methanol

[Rh2(μ-OOCCH3)2(CH3CN)6](BF4)2

[Rh2(μ-OOCCH3)2(CH3CN)6](BF4)2

2,3,5,6-tetrakis(2-pyridyl)pyrazine
25005-97-4

2,3,5,6-tetrakis(2-pyridyl)pyrazine

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Rh4(μ-OOCCH3)2(2,3,5,6-tetra-2-pyridylpirazine)2(CH3OH)4(PF6)4*2CH3OH

Rh4(μ-OOCCH3)2(2,3,5,6-tetra-2-pyridylpirazine)2(CH3OH)4(PF6)4*2CH3OH

Conditions
ConditionsYield
In methanol; dichloromethane (Rh2(OOCCH3)2(CH3CN)6)(BF4)2 dissolved in CH3OH and added to CH2Cl2 soln. of 2,3,5,6-tetra-2-pyridylpyrazine under N2 and heated for 1 h; treated with excess of (C4H9)4NPF6; soln. concd., treated with diethyl ether, solid collected by filtrn., recrystd. from a CH3OH/benzene soln.;92%
methanol
67-56-1

methanol

2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methylphenol
1186470-02-9

2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methylphenol

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

copper dichloride

copper dichloride

[CuCl(2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methylphenol)](hexafluorphosphate)*methanol

[CuCl(2-[(2-pyridylmethyl)(2'-pyridylethyl)amino-methyl]-4-methylphenol)](hexafluorphosphate)*methanol

Conditions
ConditionsYield
In methanol refluxing 1:1 mixt. of copper compd. and phenol. deriv. in methanol for 1 h, addn. of hexafluorophosphate salt; filtration, washing with cold methanol, drying in vac., elem. anal.;92%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

2-acetylpyridine hydrazone
59742-91-5

2-acetylpyridine hydrazone

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

(η5-pentamethylcyclopentadienylato)IrCl(2-(1-hydrazonoethyl)pyridine)(PF6)
1370365-92-6

(η5-pentamethylcyclopentadienylato)IrCl(2-(1-hydrazonoethyl)pyridine)(PF6)

Conditions
ConditionsYield
In ethanol Ar, Schlenk technique; mixt. of Ir-complex and pyridine-imine stirred atroom temp. for 5 min, Bu4NPF6 added; filtered, residue washed (THF, ether), dried (vac.); elem. anal.;92%
cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

C20H28CoN6(2+)*2F6P(1-)

C20H28CoN6(2+)*2F6P(1-)

Conditions
ConditionsYield
Stage #1: cobalt(II) chloride hexahydrate; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7;
Stage #2: tert-butylammonium hexafluorophosphate(V) In water
92%
tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

zinc(II) chloride
7646-85-7

zinc(II) chloride

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

(2,9-bis(2',5'-diazahexanyl)-1,10-phenanthroline)zinc(II) bis(hexafluorophosphate)

(2,9-bis(2',5'-diazahexanyl)-1,10-phenanthroline)zinc(II) bis(hexafluorophosphate)

Conditions
ConditionsYield
Stage #1: zinc(II) chloride; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7;
Stage #2: tert-butylammonium hexafluorophosphate(V) In water
92%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

tetra-n-butylammonium monocyanido(pentafluorido)phosphate

tetra-n-butylammonium monocyanido(pentafluorido)phosphate

Conditions
ConditionsYield
at 25℃; for 20h; Time; Inert atmosphere;92%
trimethylaluminium dimer

trimethylaluminium dimer

(Cl2BC5H4)Co(C5H4BCl3)
214750-04-6

(Cl2BC5H4)Co(C5H4BCl3)

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

Co(C5H4B(CH3)2)2(1+)*PF6(1-)=[Co(C5H4B(CH3)2)2]PF6
848891-30-5

Co(C5H4B(CH3)2)2(1+)*PF6(1-)=[Co(C5H4B(CH3)2)2]PF6

Conditions
ConditionsYield
In dichloromethane; toluene N2-atmosphere; stirring (room temp., 2 h), evapn. (vac.), CH2Cl2 addn., pptn. on hexane addn., filtering, washing (hexane), Bu4NPF6 addn.; crystn. (CH2Cl2, -30°C); elem. anal.;91%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

N1,N2-bis(o-tolyl)ethane-1,2-diimine
51479-97-1

N1,N2-bis(o-tolyl)ethane-1,2-diimine

[(CH3C6H4NCHCHNC6H4CH3)C5(CH3)5ClIr](1+)*PF6(1-)=[(CH3C6H4NCHCHNC6H4CH3)C5(CH3)5ClIr]PF6
405316-13-4

[(CH3C6H4NCHCHNC6H4CH3)C5(CH3)5ClIr](1+)*PF6(1-)=[(CH3C6H4NCHCHNC6H4CH3)C5(CH3)5ClIr]PF6

Conditions
ConditionsYield
In methanol addn. of diene deriv. to a suspn. of Ir complex in MeOH (in ultrasonic bath), stirred for 3 h at room temp.; concd. of soln., addn. of (C4H9)4NPF6 soln. in MeOH; ppt. collected, washed with MeOH and Et2O, dried under vac.; elem. anal.;90%
nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

(2,9-bis(2',5'-diazahexanyl)-1,10-phenanthroline)nickel(II) bis(hexafluorophosphate)

(2,9-bis(2',5'-diazahexanyl)-1,10-phenanthroline)nickel(II) bis(hexafluorophosphate)

Conditions
ConditionsYield
Stage #1: nickel(II) chloride hexahydrate; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7;
Stage #2: tert-butylammonium hexafluorophosphate(V) In water
90%
copper(II) nitrate pentahydrate

copper(II) nitrate pentahydrate

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride

C20H28CuN6(2+)*2F6P(1-)

C20H28CuN6(2+)*2F6P(1-)

Conditions
ConditionsYield
Stage #1: copper(II) nitrate pentahydrate; 2,9-di(((2'-methylamino)ethyleneamino)methyl)-1,10-phenanthroline tetrahydrochloride With sodium hydroxide In water for 2h; pH=7;
Stage #2: tert-butylammonium hexafluorophosphate(V) In water
90%
tetraacetatodiruthenium chloride

tetraacetatodiruthenium chloride

2-(pyrazin-2-yl)-1,8-naphthyridine
1338090-17-7

2-(pyrazin-2-yl)-1,8-naphthyridine

water
7732-18-5

water

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

acetonitrile
75-05-8

acetonitrile

cis-[Ru2(2-(2-pyrazinyl)-1,8-naphthyridine)2(OAc)2][PF6]2(CH3CN)(H2O)

cis-[Ru2(2-(2-pyrazinyl)-1,8-naphthyridine)2(OAc)2][PF6]2(CH3CN)(H2O)

Conditions
ConditionsYield
Stage #1: tetraacetatodiruthenium chloride; 2-(pyrazin-2-yl)-1,8-naphthyridine; tert-butylammonium hexafluorophosphate(V) In methanol Inert atmosphere; Schlenk technique; Reflux;
Stage #2: water; acetonitrile Inert atmosphere; Schlenk technique;
90%
N2,N6-bis(diethylcarbamothioyl)pyridine-2,6-dicarboxamide

N2,N6-bis(diethylcarbamothioyl)pyridine-2,6-dicarboxamide

iron(III) chloride hexahydrate

iron(III) chloride hexahydrate

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

sodium chloride
7647-14-5

sodium chloride

C51H69Fe2N15NaO6S6(1+)*F6P(1-)

C51H69Fe2N15NaO6S6(1+)*F6P(1-)

Conditions
ConditionsYield
Stage #1: N2,N6-bis(diethylcarbamothioyl)pyridine-2,6-dicarboxamide; iron(III) chloride hexahydrate; sodium chloride In methanol; water at 20℃; for 0.5h;
Stage #2: With triethylamine In methanol; water at 20℃; for 0.5h;
Stage #3: tert-butylammonium hexafluorophosphate(V) In methanol; water at 20 - 50℃; for 2h;
90%

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