D-Arabinose-1-13C

Base Information

• Chemical Name: D-Arabinose-1-13C
• CAS No.: 70849-23-9
• Molecular Formula: C5H10 O5
• Molecular Weight: 151.12
• DSSTox Substance ID: DTXSID90486793
• Wikidata: Q82328253
• Mol file: 70849-23-9.mol

Synonyms:70849-23-9;D-Arabinose-1-13C;Arabinose-1-13C;(2S,3R,4R)-2,3,4,5-Tetrahydroxy(113C)pentanal;D-(1-~13~C)Arabinose;D-Arabinose-1-13c(9ci);HY-N2353S;DTXSID90486793;D-Arabinose-1-13C, 99 atom % 13C;CS-0374667

Chemical Property of D-Arabinose-1-13C

Chemical Property:

• Melting Point: 163-165 °C(lit.)
• PSA: 97.99000
• LogP: -2.73970
• Solubility.: Water (Slightly)
• XLogP3: -2.3
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 151.05617825
• Heavy Atom Count: 10
• Complexity: 104

Purity/Quality:

98% ^*data from raw suppliers

D-Arabinose-1-13C ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C=O)O)O)O)O
• Isomeric SMILES: C([C@H]([C@H]([C@@H]([13CH]=O)O)O)O)O
• Uses: D-Arabinose-1-13C is the isotope labelled analogue of D-Arabinose (A764175), an inhibitor of the enzyme glucose dehydrogenase.

Technology Process of D-Arabinose-1-13C

There total 18 articles about D-Arabinose-1-13C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.2%

D-(1-13C)-ribose (70849-24-0,178101-87-6) → [1-(13)C]-D-arabinose (70849-23-9,178101-87-6) + D-<2-13C>arabinose (101615-87-6) + D-<2-13C>xylose (131771-69-2) + D-[1-(13)C]-lyxose (70849-22-8,178101-87-6)

Guidance literature:

624>-->resin; In water; at 92 ℃; for 6.5h;

DOI:10.1016/S0008-6215(00)90268-4

Reference yield:

L-(1-13C)ribose (70849-21-7,70849-22-8,70849-23-9,70849-24-0,178101-87-6) → C4(13)CH10O5 (478506-63-7) + L-(2-13C)arabinose (83379-39-9,83379-40-2,101615-87-6,131771-69-2) + C4(13)CH10O5 (70849-21-7,70849-22-8,70849-23-9,70849-24-0,178101-87-6) + L-(1-13C)arabinose (70849-21-7,70849-22-8,70849-23-9,70849-24-0,178101-87-6)

Guidance literature:

With ammonium molybdate; at 90 ℃; for 8h;

DOI:10.1016/S0008-6215(00)90635-9

Reference yield:

L-(1-13C)ribose (70849-21-7,70849-22-8,70849-23-9,70849-24-0,178101-87-6) → C4(13)CH10O5 (478506-63-7) + L-(2-13C)arabinose (83379-39-9,83379-40-2,101615-87-6,131771-69-2) + C4(13)CH10O5 (70849-21-7,70849-22-8,70849-23-9,70849-24-0,178101-87-6) + L-(1-13C)arabinose (70849-21-7,70849-22-8,70849-23-9,70849-24-0,178101-87-6)

Guidance literature:

With ammonium molybdate; at 90 ℃; for 8h;

DOI:10.1016/S0008-6215(00)90635-9

upstream raw materials:

D-erythrose

D-(1-¹³C)-ribose

D-<2-13C>glucose

D-[1-⁽¹³⁾C]-glucosone

Downstream raw materials:

2-benzyl<(15)N>amino-2-deoxy<2-(13)C>-D-glucononitrile

D-[2-(13)C]ribose

furan

2-methylfuran