[Mo(CO)4(Ph₂PCHMePPh₂)]

Base Information

Chemical Name:[Mo(CO)4(Ph₂PCHMePPh₂)]
CAS No.:82328-55-0
Molecular Formula:C₃₀H₂₄MoO₄P₂
Molecular Weight:606.406
Hs Code.:

[Mo(CO)4(Ph<sub>2</sub>PCHMePPh<sub>2</sub>)]

Synonyms:[Mo(CO)4(Ph₂PCHMePPh₂)]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Mo(CO)4(Ph₂PCHMePPh₂)]

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Technology Process of [Mo(CO)4(Ph₂PCHMePPh₂)]

There total 3 articles about [Mo(CO)4(Ph₂PCHMePPh₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 26743-81-7
tetracarbonyl-bis(diphenylphosphino)methane-molybdenum⁽⁰⁾

: 74-88-4
methyl iodide

: 82328-55-0
[Mo(CO)4(Ph₂PCHMePPh₂)]

Guidance literature:: With n-C₄H₉Li; TMEDA; In toluene; (N2); Mo(CO)4(dppm) in toluene; addn. of TMEDA and n-BuLi; stirring for 1 h; addn. of MeI; stirring overnight; removal of volatiles; dissolving in CH2Cl2; washing with H2O; drying of CH2Cl2 portion over MgSO4; concn. on rotary evaporator; addn. of MeOH; placing of soln. in a freezer; crystn., elem. anal.;
DOI:10.1016/j.jorganchem.2007.09.024

Reference yield: 73.0%

: 26743-81-7
tetracarbonyl-bis(diphenylphosphino)methane-molybdenum⁽⁰⁾

: 82328-55-0
[Mo(CO)4(Ph₂PCHMePPh₂)]

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; methyl iodide; In diethyl ether; benzene; a soln. of n-butyl-lithium in Et2O was added to a stirred soln. of Mo-compd. and N,N,N',N'-tetramethylethylenediamine in benzene; the mixt. wasstirred for 1 h at 20°C, then treated with CH3I, stirring at 55-60°C for 4 h;; the resultant mixt. was then cooled, H2O added and the product was isolated; recrystn. from CH2Cl2/MeOH; elem.anal.;;
DOI:10.1016/S0020-1693(00)81432-2

Reference yield: 40.0%

: 59967-36-1,65337-26-0
cis-tetracarbonylbis(piperidine)molybdenum

: 28240-60-0
1,1'-bis(diphenylphosphino)ethane

: 82328-55-0
[Mo(CO)4(Ph₂PCHMePPh₂)]

Guidance literature:: In dichloromethane; (N2); reflux of Mo(CO)4(NHC5H10)2 and Ph2PCH(Me)PPh2 in CH2Cl2 for 1 h; filtration, concn. on rotary evaporator; addn. MeOH; placing in freezer overnight; crystn., concn., cooling in the freezer; crystn.;
DOI:10.1016/j.jorganchem.2007.09.024