bis(triphenylphosphane)(acetylacetonato)iridium(I)

Base Information

Chemical Name:bis(triphenylphosphane)(acetylacetonato)iridium(I)
CAS No.:89890-74-4
Molecular Formula:C₄₁H₃₇IrO₂P₂
Molecular Weight:815.911
Hs Code.:

Synonyms:bis(triphenylphosphane)(acetylacetonato)iridium(I)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(triphenylphosphane)(acetylacetonato)iridium(I)

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Technology Process of bis(triphenylphosphane)(acetylacetonato)iridium(I)

There total 2 articles about bis(triphenylphosphane)(acetylacetonato)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 34766-88-6
(acetylacetonato)bis(η2-cis-cyclooctene)iridium(I)

: 603-35-0
triphenylphosphine

: 89890-74-4
bis(triphenylphosphane)(acetylacetonato)iridium(I)

Guidance literature:: In toluene; Ir complex in toluene treated with soln. of 2 equiv. of PPh3 in toluene,reacted for 18 h; filtered, washed (cold hexane), elem. anal.;
DOI:10.1002/ejic.201000655

Reference yield: 90.0%

: 12154-84-6
η4-1,5-cyclooctadiene-μ-2,4-pentanedionato-iridium(I)

: 89890-74-4
bis(triphenylphosphane)(acetylacetonato)iridium(I)

Guidance literature:: With triphenylphosphine; In tetrahydrofuran; soln. PPh3 in THF added to Ir(COD)(acac) under N2 and soln. refluxed for 3 h and cooled to room temp.; hexane added and allowed to stand overnight, crystals filtered and washed with Et2O; elem. anal.;

Reference yield: 90.0%

: 89890-74-4
bis(triphenylphosphane)(acetylacetonato)iridium(I)

: 37737-62-5
tris(catecholato)diboron

: Ir(triphenylphosphane)2((η6-1,2-C6H4O2)B(1,2-O2C6H4))

Guidance literature:: In toluene; byproducts: C6H4O2B(acac); toluene soln. of C6H4(OBO2C6H4)2 (0.31 mmol) added of toluene soln. of Ir(acac)(PPh3)2 (0.31 mmol), heated at 100°C for 18 h under N2; cooled to room temp., ppt. collected by suction filtration, washed with toluene; elem. anal.;
DOI:10.1002/ejic.201100057