IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX

Base Information Edit

Chemical Name:IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX
CAS No.:12154-84-6
Molecular Formula:C13H19 Ir O2
Molecular Weight:399.513
Hs Code.:
Mol file:12154-84-6.mol

Synonyms:Iridium,(1,5-cyclooctadiene)(2,4-pentanedionato)- (8CI); Iridium,(2,4-pentanedionato)(1,5-cyclooctadiene)- (7CI); Iridium, [(1,2,5,6-h)-1,5-cyclooctadiene](2,4-pentanedionato-O,O')-;Iridium, [(1,2,5,6-h)-1,5-cyclooctadiene](2,4-pentanedionato-kO,kO')- (9CI); 1,5-Cyclooctadiene, iridium complex;(Acetylacetonato)(1,5-cyclooctadiene)iridium

Suppliers and Price of IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
5mg
$ 60.00

TRC
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
2.5mg
$ 45.00

TCI Chemical
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
1g
$ 384.00

TCI Chemical
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
200mg
$ 129.00

Strem Chemicals
1,5-Cyclooctadiene(acetylacetonato)iridium(I), 99% (99.9%-Ir)
100mg
$ 39.00

Strem Chemicals
1,5-Cyclooctadiene(acetylacetonato)iridium(I), 99% (99.9%-Ir)
500mg
$ 157.00

Sigma-Aldrich
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
2g
$ 432.00

Sigma-Aldrich
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
500mg
$ 213.00

Sigma-Aldrich
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
500mg
$ 205.00

ChemSupplyAustralia
1,5-Cyclooctadiene(acetylacetonato)iridium(I), 99%
1 g
$ 258.50

Total 27 raw suppliers

Chemical Property of IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX Edit

Chemical Property:

Vapor Pressure:4.56mmHg at 25°C
Melting Point:145-150°C (dec.)
Boiling Point:152 °C at 760 mmHg
Flash Point:30 °C
PSA：17.07000
Density:g/cm³
LogP:3.40610
Storage Temp.:Inert atmosphere,Store in freezer, under -20°C
Water Solubility.:Insoluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

(Acetylacetonato)(1,5-cyclooctadiene)iridium(I) ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Uses Convenient precursor to a variety of Iridium complexes and catalysts. It is a umicore precatalysts for asymmetric and cross-coupling catalysis. Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Technology Process of IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX

There total 2 articles about IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 12112-67-3
bis(1,5-cyclooctadiene)diiridium(I) dichloride

: 123-54-6,81235-32-7
acetylacetone

: 12154-84-6
η4-1,5-cyclooctadiene-μ-2,4-pentanedionato-iridium(I)

Guidance literature:: With potassium hydroxide; In diethyl ether; water; (IrCl(COD))2 and acetylacetone sombined under N2 in degassed Et2O and aq. KOH added, soln. stirred for 30 min; water added, ether removed in vacuo, product filtered in air, washed with 2-propanol, pentane and Et2O and dried in vacuo; identified by IR and1H NMR spectra;