10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole

Base Information

Chemical Name:10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole
CAS No.:1260854-56-5
Molecular Formula:C₅₆H₃₉CoF₁₀N₄O₃
Molecular Weight:1064.93
Hs Code.:

Synonyms:10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole

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Chemical Property of 10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole

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Technology Process of 10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole

There total 7 articles about 10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 10-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)corrole

: 1260854-56-5
10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole

Guidance literature:: With cobalt(II) acetate; In acetonitrile; at 85 - 95 ℃; for 0.333333h; Microwave irradiation;
DOI:10.1021/ja108904s

Reference yield: 78.0%

: 10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)corrole

: 71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7
cobalt(II) acetate

: 1260854-56-5
10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole

Guidance literature:: In acetonitrile; other Radiation; a microwave glass tube was charged with CH3CN and corrole, the soln. was stirred at room temp. for 10 min, Co-salt was added, stirred for 10 min, sealed, subjected to microwave irradiation at 85°C for 20 min,cooled to room temp.; column chromy. on silica gel (CHCl3 -> CHCl3:CH3OH (10:1)); elem. anal.;
DOI:10.1021/ja108904s

Reference yield:

: 158399-19-0
4-formyl-5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene

: 1260854-56-5
10-(4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(pentafluorophenyl)cobalt(III)corrole

Guidance literature:: Multi-step reaction with 2 steps

1.1: trifluoroacetic acid / dichloromethane / 7 h / 20 °C

1.2: 0.25 h / 20 °C

2.1: cobalt(II) acetate / acetonitrile / 0.33 h / 85 - 95 °C / Microwave irradiation

With cobalt(II) acetate; trifluoroacetic acid; In dichloromethane; acetonitrile;
DOI:10.1021/ja108904s