C₂₇H₃₇NO₃Si

Base Information

Chemical Name:C₂₇H₃₇NO₃Si
CAS No.:1612775-38-8
Molecular Formula:C₂₇H₃₇NO₃Si
Molecular Weight:451.681
Hs Code.:

C<sub>27</sub>H<sub>37</sub>NO<sub>3</sub>Si

Synonyms:C₂₇H₃₇NO₃Si

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Chemical Property of C₂₇H₃₇NO₃Si

Chemical Property:

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Technology Process of C₂₇H₃₇NO₃Si

There total 5 articles about C₂₇H₃₇NO₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1612775-37-7
C₂₆H₃₅NO₄Si

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1612775-38-8
C₂₇H₃₇NO₃Si

Guidance literature:: Methyltriphenylphosphonium bromide; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 1.25h; Inert atmosphere;

C₂₆H₃₅NO₄Si; In tetrahydrofuran; at 0 ℃; for 2h; Inert atmosphere;
DOI:10.1021/ol501446w

Reference yield:

: 1612775-33-3
C₂₄H₃₀O₅Si

: 1612775-38-8
C₂₇H₃₇NO₃Si

Guidance literature:: Multi-step reaction with 5 steps

1.1: dmap / acetonitrile / 0.67 h / 0 °C / Inert atmosphere

2.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 0.5 h / Inert atmosphere; Reflux

3.1: trimethylaluminum / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

3.2: 1.5 h / 0 - 20 °C / Inert atmosphere

4.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 2.5 h / 20 °C / Inert atmosphere

5.1: potassium tert-butylate / tetrahydrofuran / 1.25 h / 0 °C / Inert atmosphere

5.2: 2 h / 0 °C / Inert atmosphere

With dmap; 2,2'-azobis(isobutyronitrile); potassium tert-butylate; trimethylaluminum; tri-n-butyl-tin hydride; sodium hydrogencarbonate; Dess-Martin periodane; In tetrahydrofuran; hexane; dichloromethane; toluene; acetonitrile; 2.1: |Barton-McCombie Deoxygenation / 5.1: |Wittig Olefination / 5.2: |Wittig Olefination;
DOI:10.1021/ol501446w

Reference yield:

: C₂₄H₃₂O₅Si

: 1612775-38-8
C₂₇H₃₇NO₃Si

Guidance literature:: Multi-step reaction with 6 steps

1.1: N-iodo-succinimide; tetra-(n-butyl)ammonium iodide / dichloromethane / 21 h / 20 °C / Inert atmosphere

2.1: dmap / acetonitrile / 0.67 h / 0 °C / Inert atmosphere

3.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 0.5 h / Inert atmosphere; Reflux

4.1: trimethylaluminum / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

4.2: 1.5 h / 0 - 20 °C / Inert atmosphere

5.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 2.5 h / 20 °C / Inert atmosphere

6.1: potassium tert-butylate / tetrahydrofuran / 1.25 h / 0 °C / Inert atmosphere

6.2: 2 h / 0 °C / Inert atmosphere

With dmap; N-iodo-succinimide; 2,2'-azobis(isobutyronitrile); potassium tert-butylate; trimethylaluminum; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; sodium hydrogencarbonate; Dess-Martin periodane; In tetrahydrofuran; hexane; dichloromethane; toluene; acetonitrile; 3.1: |Barton-McCombie Deoxygenation / 6.1: |Wittig Olefination / 6.2: |Wittig Olefination;
DOI:10.1021/ol501446w