N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Base Information

Chemical Name:N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester
CAS No.:144923-60-4
Molecular Formula:C₃₃H₄₄Cl₃N₃O₁₅
Molecular Weight:829.082
Hs Code.:

N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Synonyms:N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Suppliers and Price of N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

There total 6 articles about N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 24864-42-4
N-benzyloxycarbonyl-seryl-alanine tert-butyl ester

: 144923-59-1
ethyl 3,4,6-tri-O-acetyl-2-deoxy-1-thio-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

: 144923-60-4
N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Guidance literature:: With 4 A molecular sieve; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In dichloromethane; for 2.5h; Ambient temperature;
DOI:10.1016/S0957-4166(00)80230-X

Reference yield:

: 52162-39-7,100837-14-7
2-(benzylidene)amino-2-deoxy-1,3,4,6-tetra-O-acetyl-β-D-glucopyranose

: 144923-60-4
N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: HCl / acetone

3: 76.5 percent / molecular sieves 4A, boron trifluoride etherate / 1 h / Ambient temperature

4: 65 percent / molecular sieves 4A, dimethyl(methylthio)sulfoniumtrifluoromethansulfonate (DMTST) / CH₂Cl₂ / 2.5 h / Ambient temperature

With hydrogenchloride; 4 A molecular sieve; boron trifluoride diethyl etherate; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In dichloromethane; acetone;
DOI:10.1016/S0957-4166(00)80230-X

Reference yield:

: 90-76-6,90-77-7,530-23-4,579-32-8,579-33-9,643-68-5,2596-19-2,6490-68-2,6490-70-6,6490-72-8,6490-73-9,6490-74-0,14196-84-0,14196-86-2,14257-69-3,58381-21-8
2-deoxy-2-amino glucose

: 144923-60-4
N-benzyloxycarbonyl-O-<3,4,6-tri-O-acetyl-2-(N-2,2,2-trichloroethyloxycarbonyl)-amino-2-deoxy-β-D-glucopyranosyl>-seryl-alanine tert-butyl ester

Guidance literature:: Multi-step reaction with 6 steps

2: pyridine

3: HCl / acetone

5: 76.5 percent / molecular sieves 4A, boron trifluoride etherate / 1 h / Ambient temperature

6: 65 percent / molecular sieves 4A, dimethyl(methylthio)sulfoniumtrifluoromethansulfonate (DMTST) / CH₂Cl₂ / 2.5 h / Ambient temperature

With pyridine; hydrogenchloride; 4 A molecular sieve; boron trifluoride diethyl etherate; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In dichloromethane; acetone;
DOI:10.1016/S0957-4166(00)80230-X