Technology Process of C26H38O5Si
There total 6 articles about C26H38O5Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
acetic acid; tetramethylammonium triacetoxyborohydride;
In
acetonitrile;
at -35 ℃;
for 18h;
stereoselective reaction;
DOI:10.1039/c3ob27508f
- Guidance literature:
-
Multi-step reaction with 2 steps
1: methanol; toluene / 1 h / 110 °C / Sealed tube
2: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 18 h / -35 °C
With
acetic acid; tetramethylammonium triacetoxyborohydride;
In
methanol; toluene; acetonitrile;
DOI:10.1039/c3ob27508f
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: sodium hydride / nujol; tetrahydrofuran / 16.5 h / 0 °C
1.2: 3.3 h / 0 °C
2.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 6 h / Reflux
3.1: (R)-Tol-BINAP; tetrabutylammonium triphenyldifluorosilicate; copper(II) bis(trifluoromethanesulfonate) / tetrahydrofuran / 16 h / -78 °C
4.1: methanol; toluene / 1 h / 110 °C / Sealed tube
5.1: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 18 h / -35 °C
With
(R)-Tol-BINAP; copper(II) bis(trifluoromethanesulfonate); sodium hydride; acetic acid; tetrabutylammonium triphenyldifluorosilicate; tetramethylammonium triacetoxyborohydride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; methanol; nujol; ethyl acetate; toluene; acetonitrile;
3.1: |Mukaiyama Aldol Addition;
DOI:10.1039/c3ob27508f
