(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

Base Information

Chemical Name:(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate
CAS No.:1234579-98-6
Molecular Formula:C₃₆H₆₄N₃O₁₀PSi₂
Molecular Weight:786.063
Hs Code.:

(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

Synonyms:(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

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Chemical Property of (2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

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Technology Process of (2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

There total 1 articles about (2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1234579-97-5
(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-hydroxy-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

: 126429-21-8
diallyl diisopropylphosphoramidite

: 1234579-98-6
(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

Guidance literature:: (2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-hydroxy-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate; diallyl diisopropylphosphoramidite; With 1H-tetrazole; In dichloromethane; acetonitrile; at 20 ℃; for 1h; Inert atmosphere;

With tert.-butylhydroperoxide; In methanol; decane; dichloromethane; acetonitrile; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/chem.201000104

Reference yield: 90.0%

: 1234579-98-6
(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

: 115491-93-5
diallyl dicarbonate

: 1234579-99-7
(2S,3R,5R)-ethyl 2-(2-(allyloxycarbonylamino)ethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

Guidance literature:: (2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-(bis(allyloxy)phosphoryloxy)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate; With triphenylphosphine; In tetrahydrofuran; water; at 20 ℃; for 10h;

diallyl dicarbonate; With water; sodium hydrogencarbonate; In tetrahydrofuran; at 20 ℃; for 0.166667h;
DOI:10.1002/chem.201000104