(AsPh₃)₂CuCl

Base Information

• Chemical Name: (AsPh₃)₂CuCl
• CAS No.: 102481-56-1
• Molecular Formula: C₃₆H₃₀As₂ClCu
• Molecular Weight: 711.476
• Mol file: 102481-56-1.mol

Synonyms:(AsPh₃)₂CuCl

Chemical Property of (AsPh₃)₂CuCl

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (AsPh₃)₂CuCl

There total 1 articles about (AsPh₃)₂CuCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenyl-arsane (603-32-7) + copper(l) chloride → (AsPh3)2CuCl (102481-56-1)

Guidance literature:

In dichloromethane; at 20 ℃;

DOI:10.14233/ajchem.2017.20295

Reference yield: 8.9%

(AsPh3)2CuCl (102481-56-1) + K(1+)*FeCo3(1-)*12CO=K(FeCo3(CO)12) → Cu(As(C6H5)3)3(1+)*FeCo3(1-)*12CO = [Cu(As(C6H5)3)3][FeCo3(CO)12] + [FeCo3(CO)12(μ3-Cu(AsPh3))]

Guidance literature:

In toluene; byproducts: KCl; soln. of the Cu-complex added to a suspn. of the FeCo3-complex in toluene, 0.5 h; filtered, evapd. under reduced pressure, extn. with hexane afforded FeCo3(CO)12(Cu(AsPh3)), elem. anal., extn. of the residue with toluene at 40°C afforded (Cu(AsPh3)3)(FeCo3(CO)12), elem. anal.;

DOI:10.1039/DT9860000225

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + ethanol (64-17-5) + (AsPh3)2CuCl (102481-56-1) → [(AsPh3)2Cu(S2COEt)]

Guidance literature:

In dichloromethane; at 20 ℃; for 24h;

DOI:10.14233/ajchem.2017.20295

upstream raw materials:

triphenyl-arsane