Technology Process of C29H37(2)H2NO3Si
There total 5 articles about C29H37(2)H2NO3Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C23H23(2)H2NO3;
With
n-butyllithium; potassium tert-butylate;
In
tetrahydrofuran;
at -78 ℃;
for 0.166667h;
Molecular sieve;
Inert atmosphere;
tert-butyldimethylsilyl chloride;
In
tetrahydrofuran;
at -78 - 20 ℃;
regioselective reaction;
Molecular sieve;
Inert atmosphere;
DOI:10.1021/ol4034447
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: tetradeuterioacetic acid / Inert atmosphere
2.1: n-butyllithium; potassium tert-butylate / tetrahydrofuran / 0.17 h / -78 °C / Molecular sieve; Inert atmosphere
2.2: -78 - 20 °C / Molecular sieve; Inert atmosphere
With
n-butyllithium; tetradeuterioacetic acid; potassium tert-butylate;
In
tetrahydrofuran;
DOI:10.1021/ol4034447
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: n-butyllithium / tetrahydrofuran / 2 h / -78 °C / Molecular sieve; Inert atmosphere
1.2: -78 - 20 °C / Molecular sieve; Inert atmosphere
2.1: potassium hexamethylsilazane / tetrahydrofuran / 5 h / 0 °C / Molecular sieve; Inert atmosphere
2.2: 2 h / 0 - 20 °C / Molecular sieve; Inert atmosphere
3.1: tetradeuterioacetic acid / Inert atmosphere
4.1: n-butyllithium; potassium tert-butylate / tetrahydrofuran / 0.17 h / -78 °C / Molecular sieve; Inert atmosphere
4.2: -78 - 20 °C / Molecular sieve; Inert atmosphere
With
n-butyllithium; tetradeuterioacetic acid; potassium tert-butylate; potassium hexamethylsilazane;
In
tetrahydrofuran;
DOI:10.1021/ol4034447
