potassium 3-ethoxycarbonylbenzoyltrifluoroborate

Base Information

Chemical Name:potassium 3-ethoxycarbonylbenzoyltrifluoroborate
CAS No.:1622923-42-5
Molecular Formula:C₁₀H₉BF₃O₃*K
Molecular Weight:284.084
Hs Code.:

Synonyms:potassium 3-ethoxycarbonylbenzoyltrifluoroborate

Suppliers and Price of potassium 3-ethoxycarbonylbenzoyltrifluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Potassium 3-ethoxycarbonylbenzoyltrifluoroborate
1g
$ 153.00

Total 1 raw suppliers

Chemical Property of potassium 3-ethoxycarbonylbenzoyltrifluoroborate

Chemical Property:

Purity/Quality:

98%,99%, ^*data from raw suppliers

Potassium 3-ethoxycarbonylbenzoyltrifluoroborate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses Acyltrifluroborates (KAT′s) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.

Technology Process of potassium 3-ethoxycarbonylbenzoyltrifluoroborate

There total 1 articles about potassium 3-ethoxycarbonylbenzoyltrifluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 7789-23-3
potassium fluoride

: 58313-23-8
3-iodobenzoic acid methyl ester

: 1622923-36-7
(ethylthiotrifluoroborate)methane dimethyliminium zwitterion

: 1622923-42-5
potassium 3-ethoxycarbonylbenzoyltrifluoroborate

Guidance literature:: 3-iodobenzoic acid methyl ester; (ethylthiotrifluoroborate)methane dimethyliminium zwitterion; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

With acetone; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h; Inert atmosphere;

potassium fluoride; In tetrahydrofuran; hexane; water; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201403931