Tri-tert-butylphosphine tetrafluoroborate

Base Information

Chemical Name:Tri-tert-butylphosphine tetrafluoroborate
CAS No.:131274-22-1
Molecular Formula:C12H28P^.BF4
Molecular Weight:290.133
Hs Code.:29319090
European Community (EC) Number:672-603-2
DSSTox Substance ID:DTXSID80370410
Mol file:131274-22-1.mol

Synonyms:tritert-butylphosphanium,tetrafluoroborate;Tri-tert-butylphosphonium Tetrafluoroborate;

Suppliers and Price of Tri-tert-butylphosphine tetrafluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Tri-tert-butylphosphonium Tetrafluoroborate
1g
$ 312.00

TRC
Tri-tert-butylphosphonium Tetrafluoroborate
25g
$ 225.00

TRC
Tri-tert-butylphosphonium Tetrafluoroborate
10g
$ 130.00

TCI Chemical
Tri-tert-butylphosphonium Tetrafluoroborate >98.0%(T)
5g
$ 151.00

TCI Chemical
Tri-tert-butylphosphonium Tetrafluoroborate >98.0%(T)
1g
$ 51.00

SynQuest Laboratories
Tris(tert-butyl)phosphonium tetrafluoroborate
100 g
$ 288.00

SynQuest Laboratories
Tris(tert-butyl)phosphonium tetrafluoroborate
5 g
$ 48.00

SynQuest Laboratories
Tris(tert-butyl)phosphonium tetrafluoroborate
25 g
$ 96.00

Strem Chemicals
Tri-t-butylphosphonium tetrafluoroborate, 99%
1g
$ 62.00

Strem Chemicals
Tri-t-butylphosphonium tetrafluoroborate, 99%
5g
$ 248.00

Total 132 raw suppliers

Chemical Property of Tri-tert-butylphosphine tetrafluoroborate

Chemical Property:

Appearance/Colour:white to light yellow crystal powder
Melting Point:261 °C(lit.)
PSA：13.59000
LogP:5.89610
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Sensitive.:Hygroscopic
Solubility.:Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
Water Solubility.:Soluble in methylene chloride and chloroform. Slightly soluble in terahydro furan. Insoluble in hexane, toluene and water.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:290.1957807
Heavy Atom Count:18
Complexity:147

Purity/Quality:

98% ^*data from raw suppliers

Tri-tert-butylphosphonium Tetrafluoroborate ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 36/37/38-20/21/22
Safety Statements: 22-24/25-36/37/39-26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[B-](F)(F)(F)F.CC(C)(C)[PH+](C(C)(C)C)C(C)(C)C
Uses suzuki reactionHindered Phosphine salt employed with a Pd(0)-15-membered, triolefinic, macrocyle in Suzuki cross-coupling reactions of aryl bromides and chlorides. Also used in Heck coupling of non-activated vinyl tosylates with electron deficient olefins.Ligand used in the Pd-catalyzed enantioselective α?arylation of N-boc-pyrrolidine. Tri-tert-butylphosphonium Tetrafluoroborate is used in the synthesis of substituted biaryl compounds via palladium catalyzed tandem Heck-direct arylation and tandem- sequential Heck-direct arylation-hydrogenation. Also used in the synthesis of a novel organic dye with fluorenone as conjugation bridge which is used in dye sensitized solar cells.

Technology Process of Tri-tert-butylphosphine tetrafluoroborate

There total 5 articles about Tri-tert-butylphosphine tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 13716-12-6
tri-tert-butyl phosphine

: 131274-22-1
tri tert-butylphosphoniumtetrafluoroborate

Guidance literature:: With tetrafluoroboric acid; In dichloromethane; water; toluene; at 20 ℃; for 0.0833333h;
DOI:10.1016/j.dyepig.2011.03.022

Reference yield: 90.0%

: tris(tert-butyl)phosphane-borane(1:1)

: 131274-22-1
tri tert-butylphosphoniumtetrafluoroborate

Guidance literature:: With tetrafluoroboric acid diethyl ether; In dichloromethane; at 0 ℃; Inert atmosphere;
DOI:10.1021/ol2017998

Reference yield: 87.0%

: 13755-29-8
sodium tetrafluoroborate

: 13716-12-6
tri-tert-butyl phosphine

: 131274-22-1
tri tert-butylphosphoniumtetrafluoroborate

Guidance literature:: tri-tert-butyl phosphine; With hydrogenchloride; In water; at 20 ℃; for 1h;

sodium tetrafluoroborate; In water; for 1h; Reagent/catalyst;