4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester

Base Information

Chemical Name:4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester
CAS No.:180594-92-7
Molecular Formula:C₄₆H₅₉NO₁₀
Molecular Weight:785.975
Hs Code.:

Synonyms:4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester

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Chemical Property of 4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester

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Technology Process of 4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester

There total 12 articles about 4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 814-68-6,25189-84-8
acryloyl chloride

: 180594-91-6
4'-(11-Hydroxy-undecyloxy)-biphenyl-4-carboxylic acid 4-((R)-9-hydroxy-1-methyl-nonyloxy)-3-nitro-phenyl ester

: 180594-92-7
4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester

Guidance literature:: With triethylamine; In tetrahydrofuran; at 0 ℃; for 12h;
DOI:10.1021/ja961309e

Reference yield:

: 103-16-2
4-Benzyloxyphenol

: 180594-92-7
4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 94 percent / Et₃N / CH₂Cl₂ / 20 h / 0 °C

2: 98 percent / H₂ / 10percent Pd/C / ethyl acetate / 1 h / 70 °C

3: 76 percent / NaNO₃, La(NO₃)3*6H₂O, conc. aq. HCl / diethyl ether / 3 h / Ambient temperature

4: 81 percent / diethylazodicarboxylate, PPh₃ / diethyl ether / 48 h / Ambient temperature

5: 98 percent / KOH / ethanol / 3 h / 50 °C

6: 78 percent / dicyclohexylcarbodiimide, 4-(dimethylaminopyridine) / CH₂Cl₂ / 48 h

7: 1.) 9-BBN, 2.) 30percent aq. H₂O₂ / 1.) THF, 3 h, 2.) THF, EtOH, 50 deg C, 1 h

8: 33 percent / Et₃N / tetrahydrofuran / 12 h / 0 °C

With hydrogenchloride; dmap; potassium hydroxide; sodium nitrate; 9-borabicyclo[3.3.1]nonane dimer; hydrogen; dihydrogen peroxide; lanthanum(III) nitrate; triethylamine; dicyclohexyl-carbodiimide; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; ethyl acetate;
DOI:10.1021/ja961309e

Reference yield:

: 2444-21-5
(4'-benzyloxyphenyl)benzoate

: 180594-92-7
4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 98 percent / H₂ / 10percent Pd/C / ethyl acetate / 1 h / 70 °C

2: 76 percent / NaNO₃, La(NO₃)3*6H₂O, conc. aq. HCl / diethyl ether / 3 h / Ambient temperature

3: 81 percent / diethylazodicarboxylate, PPh₃ / diethyl ether / 48 h / Ambient temperature

4: 98 percent / KOH / ethanol / 3 h / 50 °C

5: 78 percent / dicyclohexylcarbodiimide, 4-(dimethylaminopyridine) / CH₂Cl₂ / 48 h

6: 1.) 9-BBN, 2.) 30percent aq. H₂O₂ / 1.) THF, 3 h, 2.) THF, EtOH, 50 deg C, 1 h

7: 33 percent / Et₃N / tetrahydrofuran / 12 h / 0 °C

With hydrogenchloride; dmap; potassium hydroxide; sodium nitrate; 9-borabicyclo[3.3.1]nonane dimer; hydrogen; dihydrogen peroxide; lanthanum(III) nitrate; triethylamine; dicyclohexyl-carbodiimide; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; ethyl acetate;
DOI:10.1021/ja961309e