(3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

Base Information

Chemical Name:(3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid
CAS No.:210691-71-7
Molecular Formula:C₃₄H₃₃ClO₅
Molecular Weight:557.086
Hs Code.:

Synonyms:(3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

Suppliers and Price of (3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

Chemical Property:

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Technology Process of (3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

There total 1 articles about (3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 210691-70-6
(2R,3R,4S)-2-Allyl-4-(4-chlorobenzoyloxy)-3-methyl-1-triphenylmethyloxypentan-4-ol

: 210691-71-7
(3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

Guidance literature:: With ruthenium trichloride; sodium periodate; In tetrachloromethane; acetonitrile; at 20 ℃; for 7h;
DOI:10.1039/a909898d

Reference yield: 80.0%

: 210691-71-7
(3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

: 210691-72-8
(R)-4-[(1R,2R)-2-(4-Chlorobenzoyloxy)-1-methylpropyl]dihydrofuran-2(2H)-one

Guidance literature:: With toluene-4-sulfonic acid; In methanol; for 24h; Ambient temperature;
DOI:10.1055/s-1998-1803

Reference yield:

: 210691-71-7
(3R,4R,5R)-5-(4-Chlorobenzoyloxy)-4-methyl-3-(triphenylmethyoxymethyl)hexanoic acid

: 139403-50-2
(4R,5R,6R)-5,6-Dimethyl-4-(phenylselanylmethyl)tetrahydro-2H-pyran-2-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: p-TsOH / methanol / 4 h / 20 °C

2.1: NaBH₄ / ethanol

2.2: 80 percent / ethanol / 10 h / Heating

3.1: n-BuLi; DIBALH / hexane; CH₂Cl₂; tetrahydrofuran / 3.08 h / -78 - -20 °C

3.2: 72 percent / aq. HCl / diethyl ether; tetrahydrofuran; CH₂Cl₂ / 24 h

With sodium tetrahydroborate; n-butyllithium; diisobutylaluminium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; 1.1: Cyclization / 2.1: Metallation / 2.2: Ring cleavage / 3.1: Reduction / 3.2: Cyclization;
DOI:10.1039/a909898d