Technology Process of [((C6H5)2Si(CH3)C(CCH3)4)2TiCl2]
There total 2 articles about [((C6H5)2Si(CH3)C(CCH3)4)2TiCl2] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
PbCl2;
In
tetrahydrofuran;
soln. of Ti complex (1 equiv.) in THF was poured on solid, vac.-dried PbCl2 (1 equiv.); mixt. was stirred at 60°C for 4 h; volatiles evapd. (vac.); residue extd. (hexane); concd.; cooled at -18°C overnight;
DOI:10.1016/S0022-328X(02)01726-6
- Guidance literature:
-
With
LiBu; AgCl;
In
tetrahydrofuran; hexane;
(Ar); soln. of LiBu in hexane was added to TiCl4 in THF; mixt. was refluxed; LiBu was reacted under stirring with cyclopentadiene in THF for 24 h at room temp.; solns. were mixed; mixt. was refluxed for 30 h and stirred with AgCl at 40°C for 5 h; elem. anal.;
DOI:10.1016/S0022-328X(02)01726-6
- Guidance literature:
-
With
Mg;
In
tetrahydrofuran;
byproducts: MgCl; high-vac. line technique; soln. of Ti complex (1 equiv.) in THF was added to Mg (1 equiv.); mixt. was stirred at 60°C for 1-3 d until Mg disappeared; volatiles distd. (vac.); residue extd. (hexane); concd.; soln. poured away; residue dissolved in toluene; concd.; cooled to -18°C; pptd.;
DOI:10.1016/S0022-328X(02)01726-6
![[Ti(C<sub>5</sub>(CH<sub>3</sub>)4(Si(C<sub>6</sub>H<sub>5</sub>)2CH<sub>3</sub>))2]](/Databaselist/images/loading.webp)
