ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate

Base Information

Chemical Name:ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate
CAS No.:1258950-96-7
Molecular Formula:C₃₂H₄₀NO₆PSi
Molecular Weight:593.732
Hs Code.:

Synonyms:ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate

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Chemical Property of ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate

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Technology Process of ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate

There total 1 articles about ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 1202003-88-0
ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(hydroxyimino)acetate

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 1258950-96-7
ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate

Guidance literature:: With triethylamine; In tetrahydrofuran; at -50 ℃;
DOI:10.1002/chem.201001036

Reference yield: 65.0%

: 1258950-96-7
ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate

: 75-16-1
methylmagnesium bromide

: 1202003-90-4
2-[5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-N-diphenylphosphinoyl-amino-propionic acid ethyl ester

Guidance literature:: In diethyl ether; toluene; at -78 ℃;
DOI:10.1002/chem.201001036

Reference yield:

: 1258950-96-7
ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate

: 75-16-1
methylmagnesium bromide

: 1262219-54-4
(R)-2-[5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-N-diphenylphosphinoyl-amino-propionic acid ethyl ester

: (S)-2-[5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-N-diphenylphosphinoyl-amino-propionic acid ethyl ester

Guidance literature:: methylmagnesium bromide; With methyllithium; quinine; In tetrahydrofuran; diethyl ether; at -70 ℃; for 0.5h; Inert atmosphere;

ethyl [5-allyloxy-2-(tert-butyldimethylsilanyloxy)-4-methoxyphenyl]-(diphenylphosphorylimino)acetate; In tetrahydrofuran; diethyl ether; for 16h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1039/c0cc03399e